Structure characterization and preliminary immune activity of a glucomannan purified from Allii Tuberosi Semen

Carbohydr Res. 2025 Mar:549:109375. doi: 10.1016/j.carres.2025.109375. Epub 2025 Jan 3.

Abstract

A novel glucomannan, named ATSW-1, was obtained from Allii Tuberosi Semen by ion and gel permeation chromatography purification. Its structure was characterized using high-performance chromatography, Fourier transform infrared spectroscopy, gas chromatography-mass spectrometry, and nuclear magnetic resonance spectroscopy. The in vitro immune activities of ATSW-1 were examined using the Cell Counting Kit-8, the neutral red phagocytosis assay, and the secretion of related cytokines. The results showed that the molecular weight of ATSW-1 was 35.9 kDa and mainly constituted of mannose, glucose, and arabinose with a molar ratio of 1:0.72:0.04. Its main backbone was composed of →4)-β-D-Glcp-(1→, →4)-β-D-Manp-(1→, and →4,6)-α-D-Manp-(1→, with the branches β-D-Glcp-(1→, α-L-Araf-(1→ and →5)-α-L-Araf-(1→ linkage substituted at C-6 position of →4)-α-D-Manp-(1 → . ATSW-1 significantly enhanced immune responses, increasing the phagocytic activity of RAW264.7 cells by 1.52 times compared to the blank control group. Further investigations revealed that ATSW-1 promotes immune activity by upregulating the NO, TNF-α, and IL-6 secretion. These findings provide a foundation for the potential development and application of Allii Tuberosi Semen polysaccharides in functional foods or immune-related therapeutics.

Keywords: Allii Tuberosi Semen; Glucomannan; Immunomodulatory activities; Structural characterization.

MeSH terms

  • Animals
  • Carbohydrate Conformation
  • Cytokines / metabolism
  • Immunologic Factors / chemistry
  • Immunologic Factors / isolation & purification
  • Immunologic Factors / pharmacology
  • Mannans* / chemistry
  • Mannans* / isolation & purification
  • Mannans* / pharmacology
  • Mice
  • Phagocytosis* / drug effects
  • RAW 264.7 Cells

Substances

  • Mannans
  • (1-6)-alpha-glucomannan
  • Immunologic Factors
  • Cytokines