Evaluating major element hydrogeochemistry and fluoride occurrence in groundwater of crystalline bedrock aquifers and associated controlling factors of Eumseong basin area, South Korea

Long-term intake of high-fluoride water can cause fluorosis in bones and teeth or damage to organs. Fluoride in groundwater is primarily derived from reactions with rocks containing fluorine-related minerals, and fluoride concentrations are elevated in groundwater that has been reacting with these rocks for a long time. The purpose of this study is to investigate the origin and distribution of fluoride in groundwater and to assess the influence of various factors, including geology, on fluoride concentrations in groundwater. The Eumseong basin and surrounding areas were selected as the study area due to the diversity of geologic factors. 139 groundwater samples and 14 rock samples were collected, with groundwater samples subjected to field water quality measurements, chemical analysis, and statistical analysis, and rock samples subjected to microscopic observation and chemical analysis. Fluoride concentration in groundwater increased with well depth, and was highest in groundwater associated with granitic rocks rich in biotite. The fluoride concentration in groundwater showed a negative correlation with the distance to the fault, suggesting that deep groundwater may preferentially flow along fault zones in certain areas. In addition, high-fluoride groundwater had depleted water-stable isotope values, which is likely to be resulted from higher degree of water-rock interaction in groundwater recharged at higher elevations. Calcite precipitation in most groundwater appears to weaken fluorite solubility control on fluoride concentration. Multivariate statistical analysis revealed that water-rock interactions generally governed fluoride and major element concentrations, with high-fluoride groundwater clearly distinguished. These findings can aid in assessing fluoride occurrence in groundwater and managing water quality in areas with similar geological characteristics.