Elastomers are of great significance in developing smart materials for information encryption, and their unique self-healing and highly flexible properties provide innovative solutions to enhance security and anti-counterfeiting effectiveness. However, challenges remain in the multifunctional combination of mechanical properties, self-healing, degradability, and luminescence of these materials. Herein, a chemodynamic covalent adaptable network (CCAN)-induced robust, self-healing, and degradable fluorescent elastomer is proposed. Thanks to the CCANs, the resulting elastomer exhibits a tensile strength of 33.44 MPa (300 times higher than that of a linear elastomer) and an elongation at break of 1265%, and its mechanical properties can be restored to about 20 MPa after 72 h of healing at room temperature, and a self-healing efficiency of 94.67% can be realized for 24 h at 70 °C. Simultaneously, the dynamic chemical balance of keto and enol structural transitions of curcumin chain segments can be driven by CCANs, realizing multi-color (from yellow to violet) display and broad wavelength (300-500 nm) excitation, which in turn enables surface read-write and color rosette and QR code pattern printing. In addition, it can also achieve adaptive degradation under biological, alkaline, and hot water conditions. This work has guiding significance for developing the next generation of high-performance multifunctional elastomer materials, which have potential applications in the field of smart anti-counterfeiting materials and smart flexible optoelectronics.
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