Synthesis, structures, and optical properties of N-heterocycle and amino acid ester-coordinated B3H7

Xi-Meng Chen; Jing-Xian Chi; Yin-Yin Li; Yi-Wen Ge; Peng Wang; Hongju Wang; Kai Jiang; Yan-Na Ma; Xuenian Chen

doi:10.1039/d4cc05845c

Synthesis, structures, and optical properties of N-heterocycle and amino acid ester-coordinated B₃H₇

Chem Commun (Camb). 2025 Jan 13. doi: 10.1039/d4cc05845c. Online ahead of print.

Authors

Xi-Meng Chen¹, Jing-Xian Chi¹, Yin-Yin Li¹, Yi-Wen Ge¹, Peng Wang¹, Hongju Wang², Kai Jiang², Yan-Na Ma³, Xuenian Chen^{1

3}

Affiliations

¹ School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Materials, Henan Normal University, Xinxiang, Henan 453007, China. [email protected].
² School of Environment, Henan Normal University, Xinxiang, Henan 453007, China.
³ College of Chemistry, Zhengzhou University, Zhengzhou, Henan 450001, China. [email protected].

PMID: 39804019
DOI: 10.1039/d4cc05845c

Abstract

A series of N-Het·B₃H₇ and AAE·B₃H₇ complexes were prepared in moderate to high yields and the single-crystal structures of products 3, 31, 34, and 59 were determined. The N-Het·B₃H₇ and AAE·B₃H₇ complexes possess high stability, endowing these products with potential applications in luminescent and boron-containing drugs. The optical properties of the representative products have been preliminarily studied.