Kinetics and mechanism of the basic hydrolysis of indomethacin and related compounds: a reevaluation

J Pharm Sci. 1983 Sep;72(9):1075-6. doi: 10.1002/jps.2600720928.

Abstract

The kinetics of the hydrolysis of indomethacin and related compounds were studied in an alkaline medium at 25 degrees. The pseudo-first-order rate constants were evaluated from log absorbance versus time plots in the ultraviolet. These compounds showed a second-order rate constant at low concentrations of hydroxide ion and a first-order rate constant at higher concentrations of hydroxide ion.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Chemistry, Pharmaceutical
  • Hydrolysis
  • Indomethacin* / analogs & derivatives*
  • Kinetics
  • Spectrophotometry, Ultraviolet

Substances

  • Indomethacin