High-performance liquid chromatographic analysis of sulfinpyrazone and its metabolites in biological fluids

J Chromatogr. 1980 Mar 14;181(3-4):417-25. doi: 10.1016/s0378-4347(00)81144-5.

Abstract

A rapid, senstivie, and specific high-performance liquid chromatographic method is described for the quantitative analysis of sulfinpyrazone and its sulfone and p-hydroxy metabolites in plasma and urine. The method uses two different procedures for sample preparation: (1) a rapid and convenient procedure using a single extraction with 1-chlorobutane and subsequent back-extraction into sodium hydroxide solution for the analysis of sulfinpyrazone and its sulfone metabolite, and (2) a more time consuming procedure using triple extraction with ethylene dichloride, a buffer wash, and back extraction into the base for the additional analysis of the p-hydroxy metabolite. The lower limit of sensitivity for fulfinpyrazone is 50 ng/ml. Concentrations of sulfinpyrazone between 0.05 and 0.1 and 50 micrograms/ml were measured with an average coefficient of variation of 3.9%, ranging from 1.5 to 6.1%.

Publication types

  • Comparative Study
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Butanes
  • Chromatography, High Pressure Liquid / methods
  • Ethylene Dichlorides
  • Humans
  • Male
  • Sulfinpyrazone / analogs & derivatives*
  • Sulfinpyrazone / blood*
  • Sulfinpyrazone / metabolism
  • Sulfinpyrazone / urine
  • Sulfones / blood
  • Sulfones / urine

Substances

  • Butanes
  • Ethylene Dichlorides
  • Sulfones
  • 4-hydroxysulfinpyrazone
  • Sulfinpyrazone
  • butyl chloride