Synthesis and biological studies on some organo-tin and lead halo and mixed halo-pseudohalo anionic complexes

Arzneimittelforschung. 1994 Feb;44(2):178-81.

Abstract

Some new anionic complexes of organo-tin(IV) and lead (IV) isolated in combination of tetraorgano-ammonium phosphonium and stibonium cation(s). L[R4-nMXnY] and L2[R2MX2Y2], where R = C2H5, C4H9 or C6H5; M = Sn or Pb; X = Y = Cl = Br, I, N3, NCS; n = 1, 2 and L = R4M1 (M1 = N, P, Sb), whose structures were confirmed by correct elemental analyses, molar conductance values, van't Hoff factor and IR spectral studies, were synthesized and evaluated for anti-convulsant activity in vivo and antiviral and antibacterial activity in vitro. A few of them exhibited promising activity. In addition, the toxicity (ALD50) and effects on the central nervous system of these complexes have been studied in mice.

MeSH terms

  • Animals
  • Anti-Bacterial Agents
  • Anti-Infective Agents / chemical synthesis
  • Anti-Infective Agents / pharmacology
  • Anticonvulsants / chemical synthesis
  • Anticonvulsants / pharmacology
  • Antifungal Agents / chemical synthesis
  • Antifungal Agents / pharmacology
  • Bacteria / drug effects
  • Central Nervous System / drug effects
  • Female
  • Fungi / drug effects
  • Lead / pharmacology*
  • Lead / toxicity
  • Lethal Dose 50
  • Male
  • Mice
  • Microbial Sensitivity Tests
  • Organometallic Compounds / chemical synthesis*
  • Organometallic Compounds / pharmacology
  • Organometallic Compounds / toxicity
  • Organotin Compounds / chemical synthesis*
  • Organotin Compounds / pharmacology*
  • Organotin Compounds / toxicity
  • Spectrophotometry, Infrared
  • Structure-Activity Relationship

Substances

  • Anti-Bacterial Agents
  • Anti-Infective Agents
  • Anticonvulsants
  • Antifungal Agents
  • Organometallic Compounds
  • Organotin Compounds
  • Lead