Efficient amidation of C-peptide deleted NPY precursors by non-endocrine cells is affected by the presence of Lys-Arg at the C-terminus

Mol Cell Endocrinol. 1993 Feb;91(1-2):135-41. doi: 10.1016/0303-7207(93)90265-l.

Abstract

Post-translational processing of peptide precursors producing amidated, biologically active peptides generally occurs in specially differentiated endocrine or neural cells. However, we have previously shown that a C-peptide-deleted precursor of neuropeptide Y (NPY1-39) in which the precursor terminates in the sequence Gly-Lys-Arg was partially amidated by the non-endocrine cell line, CHO. In the present study we show that two other non-endocrine cell lines, NIH 3T3 and BHK, also possess amidating activities and that the NPY1-39 precursor was completely converted to NPY1-36 amide by the NIH 3T3 cell line. The role of the two basic residues (Lys-Arg) in the C-terminus was studied by transfection of a construct encoding a NPY precursor terminating with glycine alone. Both the CHO and NIH 3T3 cell lines, transfected with this construct, secreted a significantly smaller fraction of NPY reactive material as amidated NPY compared to the fraction of amidated NPY secreted by the cells transfected with the NPY1-39 precursor. It is concluded that the capacity to perform C-terminal amidation appears to be a universal feature of eukaryotic cells and that the carboxypeptidase E-like enzyme influences the amidation process, beyond its known ability to remove the C-terminal basic residues.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • 3T3 Cells
  • Amides / metabolism
  • Amino Acid Sequence
  • Animals
  • Arginine*
  • Blotting, Northern
  • CHO Cells
  • Cell Line
  • Cricetinae
  • Humans
  • Kidney
  • Lysine*
  • Mice
  • Molecular Sequence Data
  • Mutagenesis, Site-Directed
  • Neuropeptide Y / chemistry
  • Neuropeptide Y / genetics
  • Neuropeptide Y / metabolism*
  • Peptide Fragments / metabolism*
  • Protein Precursors / metabolism*
  • Transfection

Substances

  • Amides
  • Neuropeptide Y
  • Peptide Fragments
  • Protein Precursors
  • Arginine
  • Lysine