Purification and biochemical characterization of a mammalian phosphatidylinositol 3,4,5-trisphosphate 5-phosphatase

J Biol Chem. 1995 Dec 29;270(52):31001-7. doi: 10.1074/jbc.270.52.31001.

Abstract

Characterization of the enzymes involved in metabolism of 3-phosphorylated inositol lipids and their subcellular localization revealed that in vitro a 5-phosphatase activity was responsible for the degradation of phosphatidylinositol 3,4,5-trisphosphate, whereas a 3-phosphatase activity hydrolyzed phosphatidylinositol 3-phosphate and/or phosphatidylinositol 3,4-bisphosphate. All these activities were localized in the cytosol. No phospholipase activities were detected. The cytosolic phosphatidylinositol 3,4,5-trisphosphate 5-phosphatase activity was purified to near homogeneity using ion exchange, affinity, and size exclusion chromatography. Characterization of the purified phosphatase revealed that it is a magnesium-dependent 5-phosphatase that is able to hydrolyze phosphatidylinositol 4,5-bisphosphate and phosphatidylinositol 3,4,5-trisphosphate. The enzyme is only partially inhibited by neomycin and vanadate but is strongly inhibited by phosphatidylinositol 4,5-bisphosphate and to a slightly lesser extent by phosphatidylinositol 4-phosphate.

MeSH terms

  • Animals
  • Brain / enzymology
  • Chromatography, High Pressure Liquid
  • Electrophoresis, Polyacrylamide Gel
  • Magnesium / metabolism
  • Phosphoric Monoester Hydrolases / antagonists & inhibitors
  • Phosphoric Monoester Hydrolases / isolation & purification*
  • Phosphoric Monoester Hydrolases / metabolism*
  • Rats
  • Substrate Specificity

Substances

  • phosphatidylinositol-3,4,5-trisphosphate 5-phosphatase
  • Phosphoric Monoester Hydrolases
  • Magnesium