Carboxydipeptidase from Boophilus microplus: a "concealed" antigen with similarity to angiotensin-converting enzyme

Insect Biochem Mol Biol. 1995 Oct;25(9):969-74. doi: 10.1016/0965-1748(95)00038-w.

Abstract

A protein, Bm91, which was first identified as a protective vaccine antigen from the tick Boophilus microplus, has regions of very strong amino acid sequence similarity to mammalian carboxydipeptidases or angiotensin converting enzymes (ACE; E.C. 3.4.15.1). This protein is now shown to share many biochemical and enzymatic properties with mammalian carboxydipeptidases. It is enzymatically active in a conventional assay for ACE using hippuryl-Gly-Gly as substrate. The hydrolysis of the C-terminal nonapeptide of the insulin B chain proceeds by sequential removal of carboxy-terminal dipeptides. The similarities extend to the dependence of activity on pH and added salt. Bm91 is inhibited by two well-characterized inhibitors of the mammalian enzymes, the drug Captopril and a nonapeptide, and the inhibition occurs in similar concentration ranges to those effective with the mammalian enzymes. However, the natural substrates of the tick enzyme are unknown. Angiotensin I itself is a poor substrate and the enzyme's natural substrates are likely to be one or more of the pharmacologically active peptides occurring in insects and arthropods.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Acid Sequence
  • Animals
  • Captopril / pharmacology
  • Dipeptidases*
  • Enzyme Inhibitors / pharmacology
  • Female
  • Membrane Glycoproteins / chemistry
  • Membrane Glycoproteins / immunology*
  • Membrane Glycoproteins / metabolism*
  • Molecular Sequence Data
  • Oligopeptides / metabolism
  • Peptidyl-Dipeptidase A / chemistry
  • Peptidyl-Dipeptidase A / immunology*
  • Substrate Specificity
  • Ticks / enzymology*

Substances

  • Bm91 protein, Boophilus microplus
  • Enzyme Inhibitors
  • Membrane Glycoproteins
  • Oligopeptides
  • hippuryl-glycyl-glycine
  • Captopril
  • Dipeptidases
  • Peptidyl-Dipeptidase A