Giardia lamblia: increased UDP-N-acetyl-D-glucosamine and N-acetyl-D-galactosamine transferase activities during encystation

Exp Parasitol. 1996 Jun;83(1):19-29. doi: 10.1006/expr.1996.0045.

Abstract

The cyst wall of Giardia lamblia is essential for survival of the parasite outside the host. N-acetyl-D-glucosamine (GalNAc) has been reported as a major terminal sugar of cyst wall glycoproteins and N-acetyl-D-galactosamine (GalNAc) as the major sugar of the fibrous insoluble cyst wall fraction. Therefore, we measured UDP-glycosyltransferase activities as the incorporation of [3H]UDP-sugar into an alcohol-insoluble product. We found that during encystation only UDP-GlcNAc and UDP-GalNAc transferase (UDP-GT) activities increased approximately three- to five-fold compared to nonencysting trophozoites. These activities were distributed approximately equally in the pellet and soluble fractions. The apparent K(m) and V(max) of UDP-GT in these fractions were similar. The activities from both fractions were dependent on Mn2+; however, the pellet enzymes were also partially activated by other metal ions. Both pUDP-GT and sUDP-GT were inhibited by uridine, UDP, and UDP sugars, but not by GlcNAc or GalNAc. Isolation and analysis of the reaction products suggest that pUDP-GT incorporate GlcNAc and GalNAc into glycoproteins, since the products were proteinase sensitive. In contrast, sUDP-GT products were resistant to proteinase treatment. Hydrolysis of the product of UDP-GlcNAc-T incorporation by trifluoroacetic acid released only glucosamine, while both glucosamine and galactosamine were released from UDP-GalNAc-T products, supporting the presence of an epimerase in Giardia which can convert GalNAc to GlcNAc during incorporation. This study suggests that at least two UDP-GT activities are induced during encystation, which are responsible for the transfer of GlcNAc and GalNAc from UDP-GlcNAc or UDP-GalNAc into both proteinase-sensitive and proteinase-resistant components of the Giardia cyst wall.

Publication types

  • Comparative Study
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Animals
  • Chitinases / metabolism
  • Chromatography, High Pressure Liquid
  • Cobalt / pharmacology
  • Endopeptidases / metabolism
  • Giardia lamblia / drug effects
  • Giardia lamblia / enzymology*
  • Giardia lamblia / physiology
  • Magnesium / pharmacology
  • Manganese / pharmacology
  • N-Acetylgalactosaminyltransferases / metabolism*
  • N-Acetylglucosaminyltransferases / metabolism*
  • Nickel / pharmacology
  • Up-Regulation
  • Uridine / pharmacology
  • Uridine Diphosphate / pharmacology
  • Uridine Diphosphate N-Acetylgalactosamine / metabolism
  • Uridine Diphosphate N-Acetylglucosamine / metabolism
  • Zinc / pharmacology

Substances

  • Cobalt
  • Manganese
  • Uridine Diphosphate N-Acetylglucosamine
  • Uridine Diphosphate
  • Uridine Diphosphate N-Acetylgalactosamine
  • Nickel
  • N-Acetylgalactosaminyltransferases
  • N-Acetylglucosaminyltransferases
  • UDP-N-acetylglucosamine transferase
  • Chitinases
  • Endopeptidases
  • Magnesium
  • Zinc
  • Uridine