Based on fixed dosages of Radix Aconiti Preparata and Rhizoma Zingiberis and six different dosages of Radix Glycyrrhizae, six different Sini Decoctions were prepared. The aconitine in these decoctions was determined by TLC-scanning. Statistical analysis was used in the experiment. It has been confirmed that the quantity of aconitine reduces with the increase of the quantity of Radix Glycyrrhizae, assuming a significant negative correlativity, r = -0.9945.