Reversible pH-dependent conformational change of reconstituted influenza hemagglutinin

J Mol Biol. 1996 Jul 19;260(3):312-6. doi: 10.1006/jmbi.1996.0402.

Abstract

Fusion between influenza virus and cell membranes is mediated by a major acid-induced conformational change of the spike glycoprotein of the viral envelope, hemagglutinin (HA). The conformational change of HA is commonly believed to be a kinetically controlled irreversible process, although the experimental evidence for this is controversial. Here we show by polarized infrared spectroscopy that the previously described acid-induced inclination of HA reconstituted in supported phospholipid bilayers is reversible in the absence, but irreversible in the presence, of bound target membranes. We also demonstrate reversible pH-dependent changes in the capability of reconstituted HA to bind target membranes. These results support a thermodynamically controlled mechanism of the conformational change of HA and provide new insight into the understanding of the energetics of influenza-mediated membrane fusion.

MeSH terms

  • Hemagglutinin Glycoproteins, Influenza Virus
  • Hemagglutinins, Viral / chemistry*
  • Hydrogen-Ion Concentration
  • Orthomyxoviridae / chemistry*
  • Protein Conformation
  • Spectroscopy, Fourier Transform Infrared / methods

Substances

  • Hemagglutinin Glycoproteins, Influenza Virus
  • Hemagglutinins, Viral