4-Nitro-1-(trimethylsilylethynyl)benzene

Acta Crystallogr C. 1998 Apr 15:54 ( Pt 4):489-91. doi: 10.1107/s0108270197012407.

Abstract

The title molecule, C11H13NO2Si, lies on a mirror plane, with only one methyl group lying out of plane. The C[symbol: see text]C triple bond has a length of 1.199 (4) A. Bond angles Si-C[symbol: see text]C and C[symbol: see text]C-C(Ar) are 177.9 (3) and 178.0 (3) degrees, respectively. The Si-Csp3 bond lengths are 1.831 (4) and 1.838 (3) A, while the Si-Csp distance is 1.839 (3) A.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Crystallography, X-Ray
  • Models, Molecular
  • Molecular Structure
  • Nitrobenzenes / chemistry*
  • Trimethylsilyl Compounds / chemistry*

Substances

  • 4-nitro-1-(trimethylsilylethynyl)benzene
  • Nitrobenzenes
  • Trimethylsilyl Compounds