High-performance liquid chromatographic assay of (+/-)-ethopropazine and its enantiomers in rat plasma

J Chromatogr B Biomed Sci Appl. 1998 Sep 18;715(2):417-23. doi: 10.1016/s0378-4347(98)00245-x.

Abstract

Two high-performance liquid chromatographic (HPLC) methods are described for determination of (+/-)-ethopropazine (ET) in rat plasma. After deproteination and liquid-liquid extraction, assay of (+/-)-ET was performed using either a C18 column (non-stereospecific assay) or an (alpha-R-naphthyl)ethylurea column (stereospecific assay). The UV detection was at 250 nm. Mean recovery was >85%. Both assays demonstrated excellent linear relationships between peak height ratios and plasma concentrations; quantitation limits were < or =25 ng/ml, based on 100 microl rat plasma. Accuracy and precision were <17% with both methods. Both methods were applied successfully to the measurement of ET plasma concentrations in rats given the drug intravenously.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Antiparkinson Agents / blood*
  • Antiparkinson Agents / chemistry
  • Antiparkinson Agents / pharmacokinetics
  • Area Under Curve
  • Chromatography, High Pressure Liquid / methods*
  • Humans
  • Male
  • Phenothiazines / blood*
  • Phenothiazines / chemistry
  • Phenothiazines / pharmacokinetics
  • Rats
  • Rats, Sprague-Dawley
  • Spectrophotometry, Ultraviolet
  • Stereoisomerism

Substances

  • Antiparkinson Agents
  • Phenothiazines
  • profenamine