The crystal structure of pneumococcal surface antigen PsaA reveals a metal-binding site and a novel structure for a putative ABC-type binding protein

Structure. 1998 Dec 15;6(12):1553-61. doi: 10.1016/s0969-2126(98)00153-1.

Abstract

Background: . The surface protein PsaA of the pathogenic bacterium Streptococcus pneumoniae plays an essential role in its virulence. PsaA is a putative ATP-binding cassette-type (ABC-type) binding protein involved in the uptake of Mn2+ and possibly Zn2+ and is considered to be both a potential drug target and and a candidate vaccine component.

Results: . The structure of PsaA has been determined to 2.0 A resolution using X-ray crystallography and is the first structure obtained for an ABC-type binding protein from a Gram-positive organism. The protein consists of two (beta/alpha)4 domains linked together by a single helix. A metal-binding site is formed in the domain interface by the sidechains of His67, His139, Glu205 and Asp280 and is occupied in the structure.

Conclusions: . The structural topology of PsaA is fundamentally different from that of other ABC-type binding proteins determined thus far in that PsaA lacks the characteristic 'hinge peptides' involved in conformational change upon solute uptake and release. In our structure, the metal-binding site is probably occupied by Zn2+. The site seems to be well conserved amongst related receptors from both Gram-positive and Gram-negative bacteria.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • ATP-Binding Cassette Transporters / metabolism*
  • Adhesins, Bacterial
  • Amino Acid Sequence
  • Bacterial Adhesion
  • Bacterial Proteins / chemistry*
  • Bacterial Proteins / metabolism
  • Binding Sites
  • Carrier Proteins*
  • Crystallography, X-Ray
  • Lipoproteins*
  • Manganese / metabolism*
  • Membrane Transport Proteins*
  • Molecular Sequence Data
  • Protein Conformation
  • Sequence Homology, Amino Acid
  • Zinc / metabolism*

Substances

  • ATP-Binding Cassette Transporters
  • Adhesins, Bacterial
  • Bacterial Proteins
  • Carrier Proteins
  • Lipoproteins
  • Membrane Transport Proteins
  • PsaA protein, Streptococcus
  • Manganese
  • Zinc

Associated data

  • PDB/1PSZ