Quenching of tryptophan (1)(pi,pi*) fluorescence induced by intramolecular hydrogen abstraction via an aborted decarboxylation mechanism.
Blancafort L, González D, Olivucci M, Robb MA.
Blancafort L, et al. Among authors: olivucci m.
J Am Chem Soc. 2002 Jun 5;124(22):6398-406. doi: 10.1021/ja016915a.
J Am Chem Soc. 2002.
PMID: 12033871
For a (1)(n,pi*) model system reported earlier (Sinicropi, A.; Pogni, R.; Basosi, R.; Robb, M. A.; Gramlich, G.; Nau, W. M.; Olivucci, M. Angew. Chem., Int. Ed. 2001, 40, 4185-4189), the ground and the excited state of the chromophore are hydrogen acce …
For a (1)(n,pi*) model system reported earlier (Sinicropi, A.; Pogni, R.; Basosi, R.; Robb, M. A.; Gramlich, G.; Nau, W. M.; …