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A highly chemoselective, diastereoselective, and regioselective epoxidation of chiral allylic alcohols with hydrogen peroxide, catalyzed by sandwich-type polyoxometalates: enhancement of reactivity and control of selectivity by the hydroxy group through metal-alcoholate bonding.
Adam W, Alsters PL, Neumann R, Saha-Möller CR, Sloboda-Rozner D, Zhang R. Adam W, et al. Among authors: neumann r. J Org Chem. 2003 Mar 7;68(5):1721-8. doi: 10.1021/jo0266386. J Org Chem. 2003. PMID: 12608784
863 results