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A new family of spin crossover complexes with a tripod ligand containing three imidazoles: synthesis, characterization, and magnetic properties of [FeIIH3LMe](NO3)2.1.5H2O, [FeIIILMe].3.5H2O, [FeIIH3LMe][FeIILMe]NO3, and [FeIIH3LMe][FeIIILMe](NO3)2 (H3LMe) = Tris[2-(((2-methylimidazol-4-yl)methylidene)amino)ethyl]amine).
Ikuta Y, Ooidemizu M, Yamahata Y, Yamada M, Osa S, Matsumoto N, Iijima S, Sunatsuki Y, Kojima M, Dahan F, Tuchagues JP. Ikuta Y, et al. Among authors: tuchagues jp. Inorg Chem. 2003 Nov 3;42(22):7001-17. doi: 10.1021/ic034495f. Inorg Chem. 2003. PMID: 14577766
A variety of spin-crossover behaviors depending on the counter anion: two-dimensional complexes constructed by NH...Cl- hydrogen bonds, [FeIIH3LMe]Cl.X (X = PF6 -, AsF6 -, SbF6 -, CF3SO3 -; H3L(Me) = Tris[2-{[(2-methylimidazol-4-yl)methylidene]amino}ethyl]amine).
Yamada M, Hagiwara H, Torigoe H, Matsumoto N, Kojima M, Dahan F, Tuchagues JP, Re N, Iijima S. Yamada M, et al. Among authors: tuchagues jp. Chemistry. 2006 Jun 2;12(17):4536-49. doi: 10.1002/chem.200500972. Chemistry. 2006. PMID: 16575927
60 results