Olefin cis-dihydroxylation versus epoxidation by non-heme iron catalysts: two faces of an Fe(III)-OOH coin.
Chen K, Costas M, Kim J, Tipton AK, Que L Jr.
Chen K, et al.
J Am Chem Soc. 2002 Mar 27;124(12):3026-35. doi: 10.1021/ja0120025.
J Am Chem Soc. 2002.
PMID: 11902894
The olefin epoxidation and cis-dihydroxylation studies described here not only corroborate the mechanistic scheme derived from our earlier studies on alkane hydroxylation by this same family of catalysts (Chen, K.; Que, L, Jr. J. Am. Chem. Soc. 2001, 123, 6327) but …
The olefin epoxidation and cis-dihydroxylation studies described here not only corroborate the mechanistic scheme derived from our earlier s …