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Olefin cis-dihydroxylation versus epoxidation by non-heme iron catalysts: two faces of an Fe(III)-OOH coin.
Chen K, Costas M, Kim J, Tipton AK, Que L Jr. Chen K, et al. J Am Chem Soc. 2002 Mar 27;124(12):3026-35. doi: 10.1021/ja0120025. J Am Chem Soc. 2002. PMID: 11902894
The olefin epoxidation and cis-dihydroxylation studies described here not only corroborate the mechanistic scheme derived from our earlier studies on alkane hydroxylation by this same family of catalysts (Chen, K.; Que, L, Jr. J. Am. Chem. Soc. 2001, 123, 6327) but …
The olefin epoxidation and cis-dihydroxylation studies described here not only corroborate the mechanistic scheme derived from our earlier s …
End-on and side-on peroxo derivatives of non-heme iron complexes with pentadentate ligands: models for putative intermediates in biological iron/dioxygen chemistry.
Roelfes G, Vrajmasu V, Chen K, Ho RY, Rohde JU, Zondervan C, La Crois RM, Schudde EP, Lutz M, Spek AL, Hage R, Feringa BL, Münck E, Que L Jr. Roelfes G, et al. Among authors: chen k. Inorg Chem. 2003 Apr 21;42(8):2639-53. doi: 10.1021/ic034065p. Inorg Chem. 2003. PMID: 12691572 Free article.
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