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Molecules with exceptionally small HOMO-LUMO gaps.
Perepichka DF, Bryce MR. Perepichka DF, et al. Among authors: bryce mr. Angew Chem Int Ed Engl. 2005 Aug 26;44(34):5370-3. doi: 10.1002/anie.200500413. Angew Chem Int Ed Engl. 2005. PMID: 16034992 No abstract available.
Engineering a remarkably low HOMO-LUMO gap by covalent linkage of a strong pi-donor and a pi-acceptor--tetrathiafulvalene-sigma-polynitrofluorene diads: their amphoteric redox behavior, electron transfer and spectroscopic properties.
Perepichka DF, Bryce MR, Batsanov AS, McInnes EJ, Zhao JP, Farley RD. Perepichka DF, et al. Among authors: bryce mr. Chemistry. 2002 Oct 18;8(20):4656-69. doi: 10.1002/1521-3765(20021018)8:20<4656::AID-CHEM4656>3.0.CO;2-1. Chemistry. 2002. PMID: 12561106
A (pi-extended tetrathiafulvalene)-fluorene conjugate. Unusual electrochemistry and charge transfer properties: the first observation of a covalent D(2+)-sigma-A(.-) redox state(1).
Perepichka DF, Bryce MR, Perepichka IF, Lyubchik SB, Christensen CA, Godbert N, Batsanov AS, Levillain E, McInnes EJ, Zhao JP. Perepichka DF, et al. Among authors: bryce mr. J Am Chem Soc. 2002 Nov 27;124(47):14227-38. doi: 10.1021/ja012518o. J Am Chem Soc. 2002. PMID: 12440922
185 results