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Page 1
Controlling metal-ligand-metal oxidation state combinations by ancillary ligand (L) variation in the redox systems [L2Ru(mu-boptz)RuL2]n, boptz = 3,6-bis(2-oxidophenyl)-1,2,4,5-tetrazine, and L = acetylacetonate, 2,2'-bipyridine, or 2-phenylazopyridine.
Patra S, Sarkar B, Maji S, Fiedler J, Urbanos FA, Jimenez-Aparicio R, Kaim W, Lahiri GK. Patra S, et al. Among authors: lahiri gk. Chemistry. 2005 Dec 23;12(2):489-98. doi: 10.1002/chem.200500295. Chemistry. 2005. PMID: 16134203
First example of mu(3)-sulfido bridged mixed-valent triruthenium complex triangle Ru(III)(2)Ru(II)(O,O-acetylacetonate)(3)(mu-O,O,gamma-C-acetylacetonate)(3)(mu(3)-S) (1) incorporating simultaneous O,O- and gamma-C-bonded bridging acetylacetonate units. Synthesis, crystal structure, and spectral and redox properties.
Patra S, Mondal B, Sarkar B, Niemeyer M, Lahiri GK. Patra S, et al. Among authors: lahiri gk. Inorg Chem. 2003 Feb 24;42(4):1322-7. doi: 10.1021/ic026221i. Inorg Chem. 2003. PMID: 12588171
An unusual dinuclear ruthenium(III) complex with a conjugated bridging ligand derived from cleavage of a 1,4-dihydro-1,2,4,5-tetrazine ring. Synthesis, structure, and UV-vis-NIR spectroelectrochemical characterization of a five-membered redox chain incorporating two mixed-valence states.
Patra S, Miller TA, Sarkar B, Niemeyer M, Ward MD, Lahiri GK. Patra S, et al. Among authors: lahiri gk. Inorg Chem. 2003 Jul 28;42(15):4707-13. doi: 10.1021/ic034131n. Inorg Chem. 2003. PMID: 12870962
Diruthenium complexes [((acac)2RuIII)2(mu-OC2H5)2], [((acac)(2RuIII)2(mu-L)](ClO4)2, and [((bpy)(2RuII)2(mu-L)](ClO4)4 [L = (NC5H4)2-N-C6H4-N-(NC5H4)2, acac = acetylacetonate, and bpy = 2,2'-bipyridine]. synthesis, structure, magnetic, spectral, and photophysical aspects.
Kar S, Chanda N, Mobin SM, Datta A, Urbanos FA, Puranik VG, Jimenez-Aparicio R, Lahiri GK. Kar S, et al. Among authors: lahiri gk. Inorg Chem. 2004 Aug 9;43(16):4911-20. doi: 10.1021/ic0498900. Inorg Chem. 2004. PMID: 15285667
Isovalent and mixed-valent diruthenium complexes [(acac)2RuII (-bpytz)RuII(acac)2] and [(acac)2RuII(-bpytz)RuIII(acac)2](ClO4) (acac = acetylacetonate and bpytz = 3,6-bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine): synthesis, spectroelectrochemical, and epr investigation.
Patra S, Sarkar B, Ghumaan S, Fiedler J, Kaim W, Lahiri GK. Patra S, et al. Among authors: lahiri gk. Inorg Chem. 2004 Sep 20;43(19):6108-13. doi: 10.1021/ic049346r. Inorg Chem. 2004. PMID: 15360263
3,6-bis(2'-pyridyl)pyridazine (L) and its deprotonated form (L - H+)- as ligands for {(acac)2Ru(n+)} or {(bpy)2Ru(m+)}: investigation of mixed valency in [{(acac)2Ru}2(mu-L - H+)]0 and [{(bpy)2Ru}2(mu-L - H+)]4+ by spectroelectrochemistry and EPR.
Ghumaan S, Sarkar B, Patra S, Parimal K, van Slageren J, Fiedler J, Kaim W, Lahiri GK. Ghumaan S, et al. Among authors: lahiri gk. Dalton Trans. 2005 Feb 21;(4):706-12. doi: 10.1039/b417530a. Epub 2005 Jan 17. Dalton Trans. 2005. PMID: 15702181
180 results