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A new coordination mode of the photometric reagent glyoxalbis(2-hydroxyanil) (H2gbha): bis-bidentate bridging by gbha2- in the redox series [(mu-gbha)[Ru(acac)2]2]n (n = -2, -1, 0, +1, +2), including a radical-bridged diruthenium(III) and a Ru(III)/Ru(IV) intermediate.
Kar S, Sarkar B, Ghumaan S, Roy D, Urbanos FA, Fiedler J, Sunoj RB, Jimenez-Aparicio R, Kaim W, Lahiri GK. Kar S, et al. Among authors: urbanos fa. Inorg Chem. 2005 Nov 28;44(24):8715-22. doi: 10.1021/ic050950r. Inorg Chem. 2005. PMID: 16296825
Diruthenium complexes [((acac)2RuIII)2(mu-OC2H5)2], [((acac)(2RuIII)2(mu-L)](ClO4)2, and [((bpy)(2RuII)2(mu-L)](ClO4)4 [L = (NC5H4)2-N-C6H4-N-(NC5H4)2, acac = acetylacetonate, and bpy = 2,2'-bipyridine]. synthesis, structure, magnetic, spectral, and photophysical aspects.
Kar S, Chanda N, Mobin SM, Datta A, Urbanos FA, Puranik VG, Jimenez-Aparicio R, Lahiri GK. Kar S, et al. Among authors: urbanos fa. Inorg Chem. 2004 Aug 9;43(16):4911-20. doi: 10.1021/ic0498900. Inorg Chem. 2004. PMID: 15285667
Unusual monodentate binding mode of 2,2'-dipyridylamine (L) in isomeric trans-(acac)2RuII(L)2, trans-[(acac)2RuIII(L)2]ClO4, and cis-(acac)2RuII(L)2 (acac = acetylacetonate). synthesis, structures, and spectroscopic, electrochemical, and magnetic aspects.
Kar S, Chanda N, Mobin SM, Urbanos FA, Niemeyer M, Puranik VG, Jimenez-Aparicio R, Lahiri GK. Kar S, et al. Among authors: urbanos fa. Inorg Chem. 2005 Mar 7;44(5):1571-9. doi: 10.1021/ic049219v. Inorg Chem. 2005. PMID: 15733000
The semiquinone-ruthenium combination as a remarkably invariant feature in the redox and substitution series [Ru(Q)(n)(acac)(3-n)](m), n = 1-3; m = (-2), -1, 0, +1, (+2); Q = 4,6-Di-tert-butyl-N-phenyl-o-iminobenzoquinone.
Das D, Das AK, Sarkar B, Mondal TK, Mobin SM, Fiedler J, Zális S, Urbanos FA, Jiménez-Aparicio R, Kaim W, Lahiri GK. Das D, et al. Among authors: urbanos fa. Inorg Chem. 2009 Dec 21;48(24):11853-64. doi: 10.1021/ic901900g. Inorg Chem. 2009. PMID: 19928984
Controlling metal-ligand-metal oxidation state combinations by ancillary ligand (L) variation in the redox systems [L2Ru(mu-boptz)RuL2]n, boptz = 3,6-bis(2-oxidophenyl)-1,2,4,5-tetrazine, and L = acetylacetonate, 2,2'-bipyridine, or 2-phenylazopyridine.
Patra S, Sarkar B, Maji S, Fiedler J, Urbanos FA, Jimenez-Aparicio R, Kaim W, Lahiri GK. Patra S, et al. Among authors: urbanos fa. Chemistry. 2005 Dec 23;12(2):489-98. doi: 10.1002/chem.200500295. Chemistry. 2005. PMID: 16134203
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