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Do single-electron lithium bonds exist? Prediction and characterization of the H3C...Li-Y (Y=H, F, OH, CN, NC, and CCH) complexes.
Li Y, Wu D, Li ZR, Chen W, Sun CC. Li Y, et al. Among authors: li zr. J Chem Phys. 2006 Aug 28;125(8):084317. doi: 10.1063/1.2339020. J Chem Phys. 2006. PMID: 16965022
Due to the formation of the single-electron Li bond, the C-H bonds of the CH(3) radical bend opposite to the LiY molecule and the Li-Y bond elongates. Abnormally, the three H(3)C...LiY (Y=CN, NC, and CCH) complexes exhibit blueshifted Li-Y …
Due to the formation of the single-electron Li bond, the C-H bonds of the CH(3) radical bend opposite to the LiY molecule and the …
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