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Reactivity of molecular dioxygen towards a series of isostructural dichloroiron(III) complexes with tripodal tetraamine ligands: general access to mu-oxodiiron(III) complexes and effect of alpha-fluorination on the reaction kinetics.
Thallaj NK, Rotthaus O, Benhamou L, Humbert N, Elhabiri M, Lachkar M, Welter R, Albrecht-Gary AM, Mandon D. Thallaj NK, et al. Among authors: rotthaus o. Chemistry. 2008;14(22):6742-53. doi: 10.1002/chem.200701967. Chemistry. 2008. PMID: 18561351
Regiospecific intramolecular O-demethylation of the ligand by action of molecular dioxygen on a ferrous complex: versatile coordination chemistry of dioxygen in FeCl(2) complexes with (2,3-dimethoxyphenyl) alpha-substituted tripods in the tris(2-pyridylmethyl)amine series.
Benhamou L, Machkour A, Rotthaus O, Lachkar M, Welter R, Mandon D. Benhamou L, et al. Among authors: rotthaus o. Inorg Chem. 2009 Jun 1;48(11):4777-86. doi: 10.1021/ic802359z. Inorg Chem. 2009. PMID: 19371064