Efficient anodic pyridination of poly(3-hexylthiophene) toward post-functionalization of conjugated polymers.
Li Y, Kamata K, Asaoka S, Yamagishi T, Iyoda T.
Li Y, et al. Among authors: iyoda t.
Org Biomol Chem. 2003 May 21;1(10):1779-84. doi: 10.1039/b211003m.
Org Biomol Chem. 2003.
PMID: 12926369
The key reaction involves efficient nucleophilic attack of the pyridine derivatives toward thiophene rings in partly oxidized polymer, i.e., doped state, in the similar manner in which anodic pyridination of electrochemically generated pi-radical cation of a series of oligothioph …
The key reaction involves efficient nucleophilic attack of the pyridine derivatives toward thiophene rings in partly oxidized polymer, i.e., …