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Half-sandwich rare-earth metal complexes bearing a C5Me4-C6H4-o-CH2NMe2 ligand: synthesis, characterization and catalytic properties for isoprene, 1-hexene and MMA polymerization.
Song T, Liu N, Tong X, Li F, Mu X, Mu Y. Song T, et al. Among authors: mu y, mu x. Dalton Trans. 2019 Dec 28;48(48):17840-17851. doi: 10.1039/c9dt04029c. Epub 2019 Nov 28. Dalton Trans. 2019. PMID: 31777884
Of these complexes, two binuclear alkyl complexes [(C(5)Me(4)-C(6)H(4)-o-CH(2)N(Me)CH(2)-mu)Ln(CH(2)SiMe(3))](2) (Ln = Sc (1a) and Y (1b)) were obtained from the alkane elimination reaction of the free ligand with Ln(CH(2)SiMe(3))(3)(THF)(2), followed by an intramolecular …
Of these complexes, two binuclear alkyl complexes [(C(5)Me(4)-C(6)H(4)-o-CH(2)N(Me)CH(2)-mu)Ln(CH(2)SiMe(3))](2) (Ln = Sc (1a) and Y …
2,850 results