Blackmond DG - Search Results

1

Mono-Oxidation of Bidentate Bis-phosphines in Catalyst Activation: Kinetic and Mechanistic Studies of a Pd/Xantphos-Catalyzed C-H Functionalization.

Ji Y, Plata RE, Regens CS, Hay M, Schmidt M, Razler T, Qiu Y, Geng P, Hsiao Y, Rosner T, Eastgate MD, Blackmond DG. Ji Y, et al. Among authors: blackmond dg. J Am Chem Soc. 2015 Oct 21;137(41):13272-81. doi: 10.1021/jacs.5b01913. Epub 2015 Oct 13. J Am Chem Soc. 2015. PMID: 26461028

2

Mechanistic insights into the Pd(BINAP)-catalyzed amination of aryl bromides: kinetic studies under synthetically relevant conditions.

Singh UK, Strieter ER, Blackmond DG, Buchwald SL. Singh UK, et al. Among authors: blackmond dg. J Am Chem Soc. 2002 Nov 27;124(47):14104-14. doi: 10.1021/ja026885r. J Am Chem Soc. 2002. PMID: 12440909

3

Insights into the origin of high activity and stability of catalysts derived from bulky, electron-rich monophosphinobiaryl ligands in the Pd-catalyzed C-N bond formation.

Strieter ER, Blackmond DG, Buchwald SL. Strieter ER, et al. Among authors: blackmond dg. J Am Chem Soc. 2003 Nov 19;125(46):13978-80. doi: 10.1021/ja037932y. J Am Chem Soc. 2003. PMID: 14611232

4

Probing the active catalyst in product-accelerated proline-mediated reactions.

Iwamura H, Wells DH Jr, Mathew SP, Klussmann M, Armstrong A, Blackmond DG. Iwamura H, et al. Among authors: blackmond dg. J Am Chem Soc. 2004 Dec 22;126(50):16312-3. doi: 10.1021/ja0444177. J Am Chem Soc. 2004. PMID: 15600319

5

Reevaluation of the mechanism of the amination of aryl halides catalyzed by BINAP-ligated palladium complexes.

Shekhar S, Ryberg P, Hartwig JF, Mathew JS, Blackmond DG, Strieter ER, Buchwald SL. Shekhar S, et al. Among authors: blackmond dg. J Am Chem Soc. 2006 Mar 22;128(11):3584-91. doi: 10.1021/ja045533c. J Am Chem Soc. 2006. PMID: 16536531

6

Mechanistic implications of pseudo zero order kinetics in kinetic resolutions.

Blackmond DG, Hodnett NS, Lloyd-Jones GC. Blackmond DG, et al. J Am Chem Soc. 2006 Jun 14;128(23):7450-1. doi: 10.1021/ja062173f. J Am Chem Soc. 2006. PMID: 16756293

7

Unusual inverse temperature dependence on reaction rate in the asymmetric autocatalytic alkylation of pyrimidyl aldehydes.

Quaranta M, Gehring T, Odell B, Brown JM, Blackmond DG. Quaranta M, et al. Among authors: blackmond dg. J Am Chem Soc. 2010 Nov 3;132(43):15104-7. doi: 10.1021/ja103204w. J Am Chem Soc. 2010. PMID: 20942400

8

Mechanistic rationalization of organocatalyzed conjugate addition of linear aldehydes to nitro-olefins.

Burés J, Armstrong A, Blackmond DG. Burés J, et al. Among authors: blackmond dg. J Am Chem Soc. 2011 Jun 15;133(23):8822-5. doi: 10.1021/ja203660r. Epub 2011 May 18. J Am Chem Soc. 2011. PMID: 21568340

9

Innate C-H trifluoromethylation of heterocycles.

Ji Y, Brueckl T, Baxter RD, Fujiwara Y, Seiple IB, Su S, Blackmond DG, Baran PS. Ji Y, et al. Among authors: blackmond dg. Proc Natl Acad Sci U S A. 2011 Aug 30;108(35):14411-5. doi: 10.1073/pnas.1109059108. Epub 2011 Aug 15. Proc Natl Acad Sci U S A. 2011. PMID: 21844378 Free PMC article.

10

A new reagent for direct difluoromethylation.

Fujiwara Y, Dixon JA, Rodriguez RA, Baxter RD, Dixon DD, Collins MR, Blackmond DG, Baran PS. Fujiwara Y, et al. Among authors: blackmond dg. J Am Chem Soc. 2012 Jan 25;134(3):1494-7. doi: 10.1021/ja211422g. Epub 2012 Jan 13. J Am Chem Soc. 2012. PMID: 22229949 Free PMC article.

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