Rao G - Search Results

1

Electronic Structures of Rhenium(II) β-Diketiminates Probed by EPR Spectroscopy: Direct Comparison of an Acceptor-Free Complex to Its Dinitrogen, Isocyanide, and Carbon Monoxide Adducts.

Lohrey TD, Rao G, Small DW, Ouellette ET, Bergman RG, Britt RD, Arnold J. Lohrey TD, et al. Among authors: rao g. J Am Chem Soc. 2020 Aug 12;142(32):13805-13813. doi: 10.1021/jacs.0c04719. Epub 2020 Jul 28. J Am Chem Soc. 2020. PMID: 32786815

2

A [4Fe-4S]-Fe(CO)(CN)-L-cysteine intermediate is the first organometallic precursor in [FeFe] hydrogenase H-cluster bioassembly.

Rao G, Tao L, Suess DLM, Britt RD. Rao G, et al. Nat Chem. 2018 May;10(5):555-560. doi: 10.1038/s41557-018-0026-7. Epub 2018 Apr 9. Nat Chem. 2018. PMID: 29632334 Free PMC article.

3

Chemical structure and bonding in a thorium(iii)-aluminum heterobimetallic complex.

Altman AB, Brown AC, Rao G, Lohrey TD, Britt RD, Maron L, Minasian SG, Shuh DK, Arnold J. Altman AB, et al. Among authors: rao g. Chem Sci. 2018 Apr 24;9(18):4317-4324. doi: 10.1039/c8sc01260a. eCollection 2018 May 14. Chem Sci. 2018. PMID: 29780563 Free PMC article.

4

Electronic Structure of Two Catalytic States of the [FeFe] Hydrogenase H-Cluster As Probed by Pulse Electron Paramagnetic Resonance Spectroscopy.

Rao G, Britt RD. Rao G, et al. Inorg Chem. 2018 Sep 4;57(17):10935-10944. doi: 10.1021/acs.inorgchem.8b01557. Epub 2018 Aug 14. Inorg Chem. 2018. PMID: 30106575 Free PMC article.

5

A Uranium Tri-Rhenium Triple Inverse Sandwich Compound.

Boreen MA, Lohrey TD, Rao G, Britt RD, Maron L, Arnold J. Boreen MA, et al. Among authors: rao g. J Am Chem Soc. 2019 Apr 3;141(13):5144-5148. doi: 10.1021/jacs.9b01331. Epub 2019 Mar 20. J Am Chem Soc. 2019. PMID: 30892880

6

Metal Bonding with 3d and 6d Orbitals: An EPR and ENDOR Spectroscopic Investigation of Ti³⁺-Al and Th³⁺-Al Heterobimetallic Complexes.

Rao G, Altman AB, Brown AC, Tao L, Stich TA, Arnold J, Britt RD. Rao G, et al. Inorg Chem. 2019 Jun 17;58(12):7978-7988. doi: 10.1021/acs.inorgchem.9b00720. Epub 2019 Jun 2. Inorg Chem. 2019. PMID: 31185562 Free PMC article.

7

Incorporation of Ni²⁺, Co²⁺, and Selenocysteine into the Auxiliary Fe-S Cluster of the Radical SAM Enzyme HydG.

Rao G, Alwan KB, Blackburn NJ, Britt RD. Rao G, et al. Inorg Chem. 2019 Oct 7;58(19):12601-12608. doi: 10.1021/acs.inorgchem.9b01293. Epub 2019 Sep 20. Inorg Chem. 2019. PMID: 31539235 Free PMC article.

8

H₂ Activation and Direct Access to Terminal Nitride and cyclo-P₃ Complexes by an Acceptor-Free Rhenium(II) β-Diketiminate.

Lohrey TD, Rao G, Britt RD, Bergman RG, Arnold J. Lohrey TD, et al. Among authors: rao g. Inorg Chem. 2019 Oct 7;58(19):13492-13501. doi: 10.1021/acs.inorgchem.9b02556. Epub 2019 Sep 24. Inorg Chem. 2019. PMID: 31550147

9

The binuclear cluster of [FeFe] hydrogenase is formed with sulfur donated by cysteine of an [Fe(Cys)(CO)₂(CN)] organometallic precursor.

Rao G, Pattenaude SA, Alwan K, Blackburn NJ, Britt RD, Rauchfuss TB. Rao G, et al. Proc Natl Acad Sci U S A. 2019 Oct 15;116(42):20850-20855. doi: 10.1073/pnas.1913324116. Epub 2019 Sep 30. Proc Natl Acad Sci U S A. 2019. PMID: 31570604 Free PMC article.

10

Lewis acid capping of a uranium(v) nitride via a uranium(iii) azide molecular square.

Boreen MA, Rao G, Villarreal DG, Watt FA, Britt RD, Hohloch S, Arnold J. Boreen MA, et al. Among authors: rao g. Chem Commun (Camb). 2020 Apr 23;56(33):4535-4538. doi: 10.1039/d0cc01356k. Chem Commun (Camb). 2020. PMID: 32207484

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