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Nickel-catalyzed stereoselective glycosylation with C(2)-N-substituted benzylidene D-glucosamine and galactosamine trichloroacetimidates for the formation of 1,2-cis-2-amino glycosides. Applications to the synthesis of heparin disaccharides, GPI anchor pseudodisaccharides, and α-GalNAc.
Mensah EA, Yu F, Nguyen HM. Mensah EA, et al. Among authors: yu f. J Am Chem Soc. 2010 Oct 13;132(40):14288-302. doi: 10.1021/ja106682m. J Am Chem Soc. 2010. PMID: 20860359
Phenanthroline-Catalyzed Stereoretentive Glycosylations.
Yu F, Li J, DeMent PM, Tu YJ, Schlegel HB, Nguyen HM. Yu F, et al. Angew Chem Int Ed Engl. 2019 May 20;58(21):6957-6961. doi: 10.1002/anie.201901346. Epub 2019 Apr 9. Angew Chem Int Ed Engl. 2019. PMID: 30920099 Free PMC article.
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