de Visser SP - Search Results

1

Defluorination of Fluorophenols by a Nonheme Iron(IV)-Oxo Species: Observation of a New Intermediate Along the Reaction.

Bagha UK, Yadav R, Mokkawes T, Satpathy JK, Kumar D, Sastri CV, de Visser SP. Bagha UK, et al. Among authors: de visser sp. Chemistry. 2023 Jul 11;29(39):e202300478. doi: 10.1002/chem.202300478. Epub 2023 Jun 2. Chemistry. 2023. PMID: 37066848

2

How does product isotope effect prove the operation of a two-state "rebound" mechanism in C-H hydroxylation by cytochrome P450?

Kumar D, de Visser SP, Shaik S. Kumar D, et al. Among authors: de visser sp. J Am Chem Soc. 2003 Oct 29;125(43):13024-5. doi: 10.1021/ja036906x. J Am Chem Soc. 2003. PMID: 14570465

3

Radical clock substrates, their C-H hydroxylation mechanism by cytochrome P450, and other reactivity patterns: what does theory reveal about the clocks' behavior?

Kumar D, de Visser SP, Sharma PK, Cohen S, Shaik S. Kumar D, et al. Among authors: de visser sp. J Am Chem Soc. 2004 Feb 18;126(6):1907-20. doi: 10.1021/ja039439s. J Am Chem Soc. 2004. PMID: 14871124

4

Oxygen economy of cytochrome P450: what is the origin of the mixed functionality as a dehydrogenase-oxidase enzyme compared with its normal function?

Kumar D, De Visser SP, Shaik S. Kumar D, et al. Among authors: de visser sp. J Am Chem Soc. 2004 Apr 28;126(16):5072-3. doi: 10.1021/ja0318737. J Am Chem Soc. 2004. PMID: 15099082

5

How do aldehyde side products occur during alkene epoxidation by cytochrome P450? Theory reveals a state-specific multi-state scenario where the high-spin component leads to all side products.

de Visser SP, Kumar D, Shaik S. de Visser SP, et al. J Inorg Biochem. 2004 Jul;98(7):1183-93. doi: 10.1016/j.jinorgbio.2004.01.015. J Inorg Biochem. 2004. PMID: 15219984

6

One oxidant, many pathways: a theoretical perspective of monooxygenation mechanisms by cytochrome P450 enzymes.

Shaik S, de Visser SP, Kumar D. Shaik S, et al. Among authors: de visser sp. J Biol Inorg Chem. 2004 Sep;9(6):661-8. doi: 10.1007/s00775-004-0576-6. Epub 2004 Jul 28. J Biol Inorg Chem. 2004. PMID: 15365903 Review.

7

External electric field will control the selectivity of enzymatic-like bond activations.

Shaik S, de Visser SP, Kumar D. Shaik S, et al. Among authors: de visser sp. J Am Chem Soc. 2004 Sep 22;126(37):11746-9. doi: 10.1021/ja047432k. J Am Chem Soc. 2004. PMID: 15366922

8

Computer-generated high-valent iron--oxo and manganese--oxo species with polyoxometalate ligands: how do they compare with the iron--oxo active species of heme enzymes?

de Visser SP, Kumar D, Neumann R, Shaik S. de Visser SP, et al. Angew Chem Int Ed Engl. 2004 Oct 25;43(42):5661-5. doi: 10.1002/anie.200453867. Angew Chem Int Ed Engl. 2004. PMID: 15495193 No abstract available.

9

Multistate reactivity in styrene epoxidation by compound I of cytochrome p450: mechanisms of products and side products formation.

Kumar D, de Visser SP, Shaik S. Kumar D, et al. Among authors: de visser sp. Chemistry. 2005 Apr 22;11(9):2825-35. doi: 10.1002/chem.200401044. Chemistry. 2005. PMID: 15744771

10

Theory favors a stepwise mechanism of porphyrin degradation by a ferric hydroperoxide model of the active species of heme oxygenase.

Kumar D, de Visser SP, Shaik S. Kumar D, et al. Among authors: de visser sp. J Am Chem Soc. 2005 Jun 8;127(22):8204-13. doi: 10.1021/ja0446956. J Am Chem Soc. 2005. PMID: 15926850

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