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Stereoelectronic interactions are too weak to explain the molecular conformation in solid state of cis-2-tert-butyl-5-(tert-butylsulfonyl)-1,3-dioxane.
Soto-Suárez FM, Rojo-Portillo T, Huerta EH, Aguilera-Cruz A, Tapia-Bárcenas A, Contreras-Cruz DA, Toscano RA, Quiróz-García B, Rojas-Aguilar A, Cortés-Guzmán F, Bacsa J, Ramírez-Gualito K, Barquera-Lozada JE, Cuevas G. Soto-Suárez FM, et al. Phys Chem Chem Phys. 2024 Mar 27;26(13):10021-10028. doi: 10.1039/d3cp04914k. Phys Chem Chem Phys. 2024. PMID: 38482754
Effect of the nO → π*C═O Interaction on the Conformational Preference of 1,3-Diketones: A Case Study of Riolozatrione Derivatives.
Tamez-Fernández JF, Soto-Suárez FM, Estrada-Chavarría YD, Quijano-Quiñones RF, Toscano RA, Cuétara-Guadarrama F, Duarte-Alaniz V, Ibarra-Rivera TR, Quiroz-García B, Martínez-Otero D, Ramírez-Gualito K, Barquera-Lozada JE, Rivas-Galindo VM, Cuevas G. Tamez-Fernández JF, et al. Among authors: soto suarez fm. J Org Chem. 2021 Jul 16;86(14):9540-9551. doi: 10.1021/acs.joc.1c00847. Epub 2021 Jul 2. J Org Chem. 2021. PMID: 34210132