Rathnayaka SC - Search Results

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Cu site differentiation in tetracopper(i) sulfide clusters enables biomimetic N₂O reduction.

Alayoglu P, Rathnayaka SC, Chang T, Wang SG, Chen YS, Mankad NP. Alayoglu P, et al. Among authors: rathnayaka sc. Chem Sci. 2024 Jul 31;15(34):13668-75. doi: 10.1039/d4sc00701h. Online ahead of print. Chem Sci. 2024. PMID: 39129770 Free PMC article.

Coordination chemistry of the Cu_Z site in nitrous oxide reductase and its synthetic mimics.

Rathnayaka SC, Mankad NP. Rathnayaka SC, et al. Coord Chem Rev. 2021 Feb 15;429:213718. doi: 10.1016/j.ccr.2020.213718. Epub 2020 Dec 19. Coord Chem Rev. 2021. PMID: 33692589 Free PMC article.

Impact of Electronic and Steric Changes of Ligands on the Assembly, Stability, and Redox Activity of Cu₄(μ₄-S) Model Compounds of the Cu_Z Active Site of Nitrous Oxide Reductase (N₂OR).

Rathnayaka SC, Hsu CW, Johnson BJ, Iniguez SJ, Mankad NP. Rathnayaka SC, et al. Inorg Chem. 2020 May 4;59(9):6496-6507. doi: 10.1021/acs.inorgchem.0c00564. Epub 2020 Apr 20. Inorg Chem. 2020. PMID: 32309936

Probing the electronic and mechanistic roles of the μ₄-sulfur atom in a synthetic Cu_Z model system.

Rathnayaka SC, Islam SM, DiMucci IM, MacMillan SN, Lancaster KM, Mankad NP. Rathnayaka SC, et al. Chem Sci. 2020 Feb 17;11(13):3441-3447. doi: 10.1039/c9sc06251c. eCollection 2020 Apr 7. Chem Sci. 2020. PMID: 34745516 Free PMC article.

N₂ O Reductase Activity of a [Cu₄ S] Cluster in the 4Cu^I Redox State Modulated by Hydrogen Bond Donors and Proton Relays in the Secondary Coordination Sphere.

Hsu CW, Rathnayaka SC, Islam SM, MacMillan SN, Mankad NP. Hsu CW, et al. Among authors: rathnayaka sc. Angew Chem Int Ed Engl. 2020 Jan 7;59(2):627-631. doi: 10.1002/anie.201906327. Epub 2019 Nov 14. Angew Chem Int Ed Engl. 2020. PMID: 31661177 Free PMC article.

Multinuclear Cu(I) Clusters Featuring a New Triply Bridging Coordination Mode of Phosphaamidinate Ligands.

Rathnayaka SC, Lindeman SV, Mankad NP. Rathnayaka SC, et al. Inorg Chem. 2018 Aug 6;57(15):9439-9445. doi: 10.1021/acs.inorgchem.8b01422. Epub 2018 Jul 13. Inorg Chem. 2018. PMID: 30003779 Free PMC article.

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