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Dinitrogen reduction chemistry with scandium provides a complex with two side-on (N[double bond, length as m-dash]N)2- ligands bound to one metal: (C5Me5)Sc[(µ-η2:η2-N2)Sc(C5Me5)2]2.
Chem Sci. 2024 Aug 30;15(39):16069-78. doi: 10.1039/d4sc03977g. Online ahead of print.
Chem Sci. 2024.
PMID: 39309095
Free PMC article.
The Scandium(II) Carbonyl Complex (C5H2tBu3)2Sc(CO) and Its Isocyanide Analog (C5H2tBu3)2Sc(CNC6H3Me2-2,6).
Queen JD, Goudzwaard QE, Rajabi A, Ziller JW, Furche F, Evans WJ.
Queen JD, et al. Among authors: goudzwaard qe.
J Am Chem Soc. 2024 Sep 11;146(36):24770-24775. doi: 10.1021/jacs.4c09021. Epub 2024 Aug 27.
J Am Chem Soc. 2024.
PMID: 39190778
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