Adenosylmethionine-dependent synthesis of the glycyl radical in pyruvate formate-lyase by abstraction of the glycine C-2 pro-S hydrogen atom. Studies of [2H]glycine-substituted enzyme and peptides homologous to the glycine 734 site.
Frey M, Rothe M, Wagner AF, Knappe J.
Frey M, et al. Among authors: knappe j.
J Biol Chem. 1994 Apr 29;269(17):12432-7.
J Biol Chem. 1994.
PMID: 8175649
Free article.
V., Frey, M., Neugebauer, F.A., Schafer, W., and Knappe, J. (1992) Proc. Natl. Acad. Sci. U. S. A. 89, 996-1000). Studying radical synthesis with [2-2H]glycine-labeled PFL, we have now found stoichiometric incorporation of a 2H atom into the 5'-deoxyadenosine (dAdo) …
V., Frey, M., Neugebauer, F.A., Schafer, W., and Knappe, J. (1992) Proc. Natl. Acad. Sci. U. S. A. 89, 996-1000). Studying rad …