Na5Co15.5Te6O36: An S=12 stacked Ising kagome antiferromagnet with a partially disordered ground state

Z. Y. Zhao, X. Y. Yue, J. Y. Li, N. Li, H. L. Che, X. F. Sun, and Z. Z. He
Phys. Rev. B 105, 144406 – Published 7 April 2022
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Abstract

S=12 Ising kagome antiferromagnets (KAFs) are rare in reality. In this paper, we report the magnetic ground state and field-induced transitions of an S=12 Ising antiferromagnet with a stacked kagome geometry, Na5Co15.5Te6O36. Upon cooling, magnetic susceptibility measurements reveal three successive magnetic transitions at T1 = 45.2 K, T2 = 35.4 K, and T3 20 K. When the magnetic field is applied along the Ising c axis, a strikingly anomalous initial magnetization lying outside the hysteresis loop is observed below T3. Through detailed characterizations, the magnetic field vs temperature phase diagram is established. A partially disordered antiferromagnetic state is proposed below T1, which becomes frozen below T3. Na5Co15.5Te6O36 is therefore a promising candidate for S=12 Ising KAFs, and this unique composite structure may shed light on the exploratory path for S=12 Ising KAFs.

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  • Received 7 December 2021
  • Accepted 29 March 2022

DOI:https://doi.org/10.1103/PhysRevB.105.144406

©2022 American Physical Society

Physics Subject Headings (PhySH)

Condensed Matter, Materials & Applied Physics

Authors & Affiliations

Z. Y. Zhao1,*, X. Y. Yue2, J. Y. Li1, N. Li3, H. L. Che3, X. F. Sun2,3, and Z. Z. He1

  • 1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China
  • 2Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui 230601, People's Republic of China
  • 3Department of Physics, Hefei National Laboratory for Physical Sciences at Microscale, and Key Laboratory of Strongly-Coupled Quantum Matter Physics (CAS), University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China

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Issue

Vol. 105, Iss. 14 — 1 April 2022

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