Calcium iodate: Difference between revisions

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{{One source|date=November 2023}}
{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 401942457476998750
| ImageFile = Calcium iodate.png
| ImageSize = 200px
| IUPACName = Calcium diiodate
| OtherNames = Lautarite
| Section1 = {{Chembox Identifiers
| InChI = 1/Ca.2HIO3/c;2*2-1(3)4/h;2*(H,2,3,4)/q+2;;/p-2
| SMILES = [Ca+2].[O-]I(=O)=O.[O-]I(=O)=O
| InChIKey = UHWJJLGTKIWIJO-NUQVWONBAT
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
Line 14 ⟶ 16:
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = UHWJJLGTKIWIJO-UHFFFAOYSA-L
| CASNo_Ref = {{cascite|correct|??CAS}}
| CASNo = 7789-80-2
| CASOtherCASNo_Comment = (anhydrous)<br/>10031-33-1 (hexahydrate)
| CASNo2_Ref = {{cascite|changed|??}}
| EC-number = 232-191-3
| CASNo2 = 10031-33-1
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| CASNo2_Comment = (hexahydrate)
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = L8MN4Y57BR
| UNII_Comment = (anhydrous)
| EC-numberEC_number = 232-191-3
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 23021
| PubChem = 24619
}}
| Section2 = {{Chembox Properties
| Formula = Ca(IO<sub>3</sub>)<sub>2</sub>
| MolarMass = 389.88 g/mol (anhydrous)<br />407.90 g/mol (monohydrate)
| Appearance = white solid
| ExactMass = 389.741015
| Density = 4.519 g/cm<sup>3</sup> (monohydrate)
| Appearance = white solid
| MeltingPtC = 540
| Density = 4.519 g/cm<sup>3</sup> (monohydrate)
| MeltingPtMeltingPt_notes = 540 °C (monohydrate)
| BoilingPt = decomposes
| Solubility = 0.09 g/100 mL (0 °C) <br> 0.24 g/100 mL (20 °C) <br> 0.67 g/100 mL (90 °C)
| SolubilityProduct = 6.47{{e|-6}}
| SolubleOther = soluble in [[nitric acid]] <br> insoluble in [[ethanol|alcohol]]
| MagSus = -101.4·10<sup>−6</sup> cm<sup>3</sup>/mol }}
|Section3={{Chembox Structure
| CrystalStruct = monoclinic (anhydrous) <br> cubic (monohydrate) <br> orthorhombic (hexahydrate)
}}
| Section3 Section7= {{Chembox StructureHazards
| FlashPt = non-flammable
| CrystalStruct = monoclinic (anhydrous) <br> cubic (monohydrate) <br> orthorhombic (hexahydrate)
}}
| Section7 = {{Chembox Hazards
| EUIndex = not listed
| FlashPt = non-flammable
}}
}}
 
'''Calcium iodate''' is any of two [[inorganic compound]]s with the formula Ca(IO<sub>3</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>x</sub>, where x = 0 or 1. Both are colourless salts that occur as the minerals [[lautarite]] and [[bruggenite]], respectively. A third mineral form of calcium iodate is [[dietzeite]], a salt containing [[Monochromate|chromate]] with the formula Ca<sub>2</sub>(IO<sub>3</sub>)<sub>2</sub>CrO<sub>4</sub>.<ref name=Ullmann>{{Ullmann |doi=10.1002/14356007.a14_381.pub2 |title=Iodine and Iodine Compounds |year=2015 |last1=Lyday |first1=Phyllis A. |last2=Kaiho |first2=Tatsuo |pages=1–13 }}</ref> These minerals are the most common compounds containing [[iodate]].
'''Calcium iodate''' (also called '''lautarite''') is a compound of [[calcium]] and [[iodate]] [[anion]]. Its formula is Ca(IO<sub>3</sub>)<sub>2</sub>. It is used as a [[dough conditioner]]. Calcium iodate is an oxidant added to lotions and ointments as an [[antiseptic]] and [[deodorant]].<ref>[http://cancerweb.ncl.ac.uk/cgi-bin/omd?calcium+iodate Calcium iodate] from the Online Medical Dictionary</ref> It may be formed by the anodic oxidation of [[calcium iodide]] or by passing [[chlorine]] into a hot solution of lime in which [[iodine]] has been dissolved. Also can be used in [[chicken feed]] as a supplement.
 
==Production and uses==
Lautarite, described as ''the'' most important mineral source of iodine, is mined in the [[Atacama Desert]].<ref name=Ullmann/> Processing of the ore entails reduction of its aqueous extracts with [[sodium bisulfite]] to give [[sodium iodide]]. This [[Comproportionation|comproportionation reaction]] is a major source of the sodium iodide.<ref name=Ullmann/>
 
Calcium iodate can be produced by the anodic oxidation of [[calcium iodide]] or by passing [[chlorine]] into a hot solution of lime in which [[iodine]] has been dissolved.
 
Calcium iodate is used as an iodine supplement in [[chicken feed]].<ref name=Ullmann/> [[Ethylenediamine dihydroiodide]] (EDDI) is a more typical source of nutritional [[iodine]].
 
==References==
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{{Calcium compounds}}
{{Iodates}}
 
[[Category:Antiseptics]]
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[[Category:Iodates]]
[[Category:Oxidizing agents]]
 
{{inorganic-compound-stub}}
 
[[ar:يودات الكالسيوم]]
[[fa:کلسیم یدات]]
[[fr:Iodate de calcium]]
[[nl:Calciumjodaat]]
[[ja:ヨウ素酸カルシウム]]
[[pl:Jodan wapnia]]
[[fi:Kalsiumjodaatti]]
[[tr:Kalsiyum iyodat]]