Nickel–metal hydride battery: Difference between revisions

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This doesn't need clarification. Stated reasons for clarification were that a month was too long a time frame because of fast initial voltage drop. Thats not self discharge. That's just a battery returning to open circuit voltage after charging. A month is if anything a shorter timeframe than typically used. Other reason was the person asking for clarification didn't understand the use of the term low self discharge. Low self discharge is a type of NiMH battery. It would be indicated on the b...
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→‎History: Reason for requesting clarification not valid. Difficult to understand logic behind request.
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{{See also|History of the battery}}
 
Work on NiMH batteries began at the [[Battelle Memorial Institute|Battelle]]-Geneva Research Center following the technology's invention in 1967. It was based on [[sintering|sintered]] Ti<sub>2</sub>Ni+TiNi+x alloys and NiOOH electrodes.{{clarify|reason=Which electrode is this? Deleting 'anode' or 'cathode' has not removed the ambiguity.|date=January 2013}} Development was sponsored over nearly two decades by [[Daimler-Benz]] and by [[Volkswagen AG]] within Deutsche Automobilgesellschaft, now a subsidiary of [[Daimler AG]]. The batteries' specific energy reached 50&nbsp;W·h/kg (180&nbsp;kJ/kg), specific power up to 1000&nbsp;W/kg and a life of 500 [[charge cycle]]s (at 100% [[depth of discharge]]). [[Patent]] applications were filed in European countries (priority: Switzerland), the United States, and Japan. The patents transferred to Daimler-Benz.<ref>The US patent is {{cite patent | country=US | status=patent | number = 3824131A | title = Negative electrode of titanium–nickel alloy hydride phases | invent1 = Dr. Klaus Beccu | assign1 = Battelle-Geneva R&D Center}}. For the performance data, see the "Examples" section.</ref>
 
Interest grew in the 1970s with the commercialisation of the [[nickel–hydrogen battery]] for satellite applications. Hydride technology promised an alternative, less bulky way to store the hydrogen. Research carried out by [[Philips|Philips Laboratories]] and France's [[French National Centre for Scientific Research|CNRS]] developed new high-energy hybrid alloys incorporating [[rare-earth metal]]s for the negative electrode. However, these suffered from alloy instability in [[alkaline]] [[electrolyte]] and consequently insufficient cycle life. In 1987, Willems and Buschow demonstrated a successful battery based on this approach (using a mixture of La<sub>0.8</sub>Nd<sub>0.2</sub>Ni<sub>2.5</sub>Co<sub>2.4</sub>Si<sub>0.1</sub>), which kept 84% of its charge capacity after 4000 charge–discharge cycles. More economically viable alloys using [[mischmetal]] instead of [[lanthanum]] were soon developed. Modern NiMH cells were based on this design.<ref name="rdjapan">{{cite journal | last1=Nii | first1=K. | last2=Amano | first2 = M. | year = 1997 | title = R & D of Hydrogen Absorbing Alloys in Japan | journal = Acta Metallurgica Sinica | volume = 10 | issue = 3 | pages = 249–255 | url = http://www.amse.org.cn/EN/abstract/abstract13633.shtml | access-date = 10 September 2011}}</ref> The first consumer-grade NiMH cells became commercially available in 1989.<ref>[http://www.economist.com/displaystory.cfm?STORY_ID=10789409 In search of the perfect battery], ''[[The Economist]]'', 6 March 2008.</ref>