Aluminium diboride: Difference between revisions

Page 1
Page 2
Content deleted Content added
No edit summary
No edit summary
 
(23 intermediate revisions by 18 users not shown)
Line 1:
{{chembox
| verifiedrevid = 399501392418541969
| Watchedfields = changed
| ImageFile = Magnesium-diboride-3D-balls.png
| verifiedrevid = 399501392
| ImageFile = Magnesium-diboride-3D-balls.png
| ImageSize =
| IUPACName = aluminium diboride
| OtherNames = aluminium boride<br>aluminum diboride
| Section1 = {{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 21171253
| PubChem = 24884166
| InChI = 1/Al.B2/c;1-2/q-2;+2/rAlB2/c1-2-3-1
| InChIKey = XGNZNBRDPPLKTC-DOGMWQOPAK
Line 15:
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = XGNZNBRDPPLKTC-UHFFFAOYSA-N
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 12041-50-8
| EINECS = 234-923-7
| SMILES = B1=B[Al]1
}}
| Section2 = {{Chembox Properties
| Formula = AlB<sub>2</sub>
| MolarMass = 48.604 g/mol<ref name=b92>{{RubberBible92nd|page=4.45}}</ref>
| Appearance = Copper-red solid
| Density = 3.19 g/cm³<sup>3</sup><ref name=b92/>
| MeltingPt = >920 °C
| MeltingPtC = 1655
| MeltingPt_notes = (decomposes)<ref name=b92/>
| BoilingPt =
| Solubility = Insoluble in waterinsoluble
}}
| Section3 = {{Chembox Structure
| Structure_ref =<ref>{{cite journal|doi=10.1021/ja01604a003|title=The Preparation of Aluminium Diboride, AlB21|journal=Journal of the American Chemical Society|volume=78|issue=23|pages=5977–5978|year=1956|last1=Felten|first1=Edward J}}</ref>
| CrystalStruct = Hexagonal, [[Pearson symbol|hP3]]
| SpaceGroup = P6/mmm, No. 191
| LattConst_a = 0.3009 nm
| LattConst_b = 0.3009 nm
| LattConst_c = 0.3262 nm,
| LattConst_alpha = 90
| LattConst_beta = 90
| LattConst_gamma = 120
| UnitCellFormulas =1
}}
|Section4={{Chembox Thermochemistry
| DeltaHf = -151 kJ/mol
| Entropy = 34.7 J/mol K
| HeatCapacity = 43.6 J/mol K
}}
| Section7 = {{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionAutoignitionPt =
}}
}}
'''Aluminium diboride''' (AlB<sub>2</sub>) is a [[chemical compound]] made from the metal [[aluminium]] and the non-metal[[metalloid]] [[boron]]. It is one of two compounds of aluminium and boron, the other being [[aluminium dodecaboride|AlB<sub>12</sub>]], thatwhich are both commonly referred to as aluminium boride.
 
Structurally the B atoms form [[graphite]] -like sheets with Al atoms between them, and this is very similar to the structure of [[magnesium diboride]]. Single crystals of AlB<sub>2</sub> exhibit metallic conductivity along the axis parallel to the basal hexagonal plane.<ref>{{cite "journal|title=On the electronic and structural properties of aluminumaluminium diboride Al<sub>0.9</sub>B<sub>2</sub>"|journal=Journal of Solid State Chemistry |volume=177 |issue=2 |pages=389 |doi=10.1016/j.jssc.2002.12.001 |year=2004 |last1=Burkhardt, Ulrich;|first1=U |last2=Gurin, |first2=Vladimir; |last3=Haarmann, |first3=Frank; |last4=Borrmann, |first4=Horst; |last5=Schnelle, |first5=Walter; |last6=Yaresko, |first6=Alexander; |last7=Grin, |first7=Yuri [http://dx|bibcode=2004JSSCh.doi177.org/10.1016/j.jssc.2002.12.001389B Journal of Solid State Chemistry 177 (2004) 389-394]}}</ref>
 
Aluminium boride is considered a hazardous substance as it reacts with [[acid]]s and [[hydrogen]] gas to produce toxic gases. For example, it reacts with hydrochloric acid to release [[borane]] and [[aluminium chloride]].
 
The crystal structure of AlB<sub>2</sub> is often used as a prototype structure to describe [[intermetallic compounds]]. There are a large number of [[structure type]]s that fall within the AlB<sub>2</sub> structural family.<ref>{{cite journal | last1=Hoffmann | first1=R.-D. | last2=Pöttgen | first2=Rainer | title=AlB<sub>2</sub>-related intermetallic compounds – a comprehensive view based on group-subgroup relations | journal=Zeitschrift für Kristallographie - Crystalline Materials | publisher=Walter de Gruyter GmbH | volume=216 | issue=3 | date=2001-01-01 | pages=127–145 | issn=2196-7105 | doi=10.1524/zkri.216.3.127.20327 | bibcode=2001ZK....216..127H | s2cid=98251655 }}</ref>
 
==See also==
*[[borideBoride]]
 
==External links==
*[http://nautilus.fis.uc.pt/st2.5/scenes-e/elem/e00530.html "Boron"];
 
== References ==
{{reflist}}
 
==External links==
*[https://web.archive.org/web/20081218043037/http://nautilus.fis.uc.pt/st2.5/scenes-e/elem/e00530.html "Boron"];
 
{{Aluminium compounds}}
{{Borides}}
 
[[Category:Borides]]
Line 60 ⟶ 78:
 
{{Inorganic-compound-stub}}
 
[[ar:ثنائي بوريد ألومنيوم]]
[[ja:二ホウ化アルミニウム]]