Vanadium(III) sulfate: Difference between revisions
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| IUPACName = Vanadium(III) sulfate |
| IUPACName = Vanadium(III) sulfate |
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'''Vanadium(III) sulfate''' is the [[inorganic compound]] with the formula V<sub>2</sub>(SO<sub>4</sub>)<sub>3</sub>. It is a pale yellow solid that is stable to air, in contrast to most vanadium(III) compounds. It slowly dissolves in water to give the green [[Metal aquo complex|aquo complex]] [V(H<sub>2</sub>O)<sub>6</sub>]<sup>3+</sup>. |
'''Vanadium(III) sulfate''' is the [[inorganic compound]] with the formula V<sub>2</sub>(SO<sub>4</sub>)<sub>3</sub>. It is a pale yellow solid that is stable to air, in contrast to most vanadium(III) compounds. It slowly dissolves in water to give the green [[Metal aquo complex|aquo complex]] [V(H<sub>2</sub>O)<sub>6</sub>]<sup>3+</sup>. |
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The compound is prepared by treating V<sub>2</sub>O<sub>5</sub> in [[sulfuric acid]] with elemental [[sulfur]]:<ref>{{cite |
The compound is prepared by treating V<sub>2</sub>O<sub>5</sub> in [[sulfuric acid]] with elemental [[sulfur]]:<ref>{{cite book | doi = 10.1002/9780470132388.ch28| chapter = Vanadium(III) Sulfate| title = Inorganic Syntheses| date = 1963| last1 = Claunch| first1 = Robert T.| last2 = Jones| first2 = Mark M.| last3 = Wolsey| first3 = Wayne C.| volume = 7| pages = 92–94| isbn = 978-0-470-13166-4}}</ref> |
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:{{chem2 | V2O5 + S + 3 H2SO4 -> V2(SO4)3 + SO2 + 3 H2O }} |
:{{chem2 | V2O5 + S + 3 H2SO4 -> V2(SO4)3 + SO2 + 3 H2O }} |
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This transformation is a rare example of a reduction by elemental sulfur. |
This transformation is a rare example of a reduction by elemental sulfur. |
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Latest revision as of 16:07, 30 June 2024
6)2(SO4)3.svg)
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| Names | |
|---|---|
| IUPAC name
Vanadium(III) sulfate
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| Other names
Vanadium trisulfate
Divanadium trisulfate | |
| Identifiers | |
| ChemSpider | |
| ECHA InfoCard | 100.033.827 |
| EC Number |
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PubChem CID
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| UNII | |
CompTox Dashboard (EPA)
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| Properties | |
| V2(SO4)3 | |
| Molar mass | 390.074 g/mol |
| Appearance | Yellow powder |
| Melting point | 400 °C (752 °F; 673 K) Decomposes |
| Slightly soluble | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Vanadium(III) sulfate is the inorganic compound with the formula V2(SO4)3. It is a pale yellow solid that is stable to air, in contrast to most vanadium(III) compounds. It slowly dissolves in water to give the green aquo complex [V(H2O)6]3+.
The compound is prepared by treating V2O5 in sulfuric acid with elemental sulfur:[2]
- V2O5 + S + 3 H2SO4 → V2(SO4)3 + SO2 + 3 H2O
This transformation is a rare example of a reduction by elemental sulfur.
When heated in vacuum at or slightly below 410 °C, it decomposes into vanadyl sulfate (VOSO4) and SO2. Vanadium(III) sulfate is stable in dry air but upon exposure to moist air for several weeks forms a green hydrate form.
Vanadium(III) sulfate is a reducing agent.
References
[edit]- ^ Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, FL: CRC Press, pp. 4–93, ISBN 0-8493-0594-2
- ^ Claunch, Robert T.; Jones, Mark M.; Wolsey, Wayne C. (1963). "Vanadium(III) Sulfate". Inorganic Syntheses. Vol. 7. pp. 92–94. doi:10.1002/9780470132388.ch28. ISBN 978-0-470-13166-4.
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