Nitrosylsulfuric acid: Difference between revisions
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:HNO<sub>2</sub> + H<sub>2</sub>SO<sub>4</sub> → NOHSO<sub>4</sub> + H<sub>2</sub>O |
:HNO<sub>2</sub> + H<sub>2</sub>SO<sub>4</sub> → NOHSO<sub>4</sub> + H<sub>2</sub>O |
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It can also be prepared by the reaction of [[nitric acid]] and [[sulfur dioxide]].<ref>{{ |
It can also be prepared by the reaction of [[nitric acid]] and [[sulfur dioxide]].<ref>{{Cite book |author1=Coleman, G. H. |author2=Lillis, G. A. |author3=Goheen, G. E. |title= Nitrosyl Chloride |year= 1939 |volume= 1 |pages= 55–59 |doi= 10.1002/9780470132326.ch20 |series=Inorganic Syntheses |isbn=9780470132326}} This procedure generates the nitrosylsulfuric acid as an intermediate en route to NOCl.</ref> |
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NOHSO<sub>4</sub> is used in [[organic chemistry]] to prepare [[diazonium salt]]s from [[amine]]s, for example in the [[Sandmeyer reaction]]. Related NO-delivery reagents include [[nitrosonium tetrafluoroborate]] ([NO]BF<sub>4</sub>) and [[nitrosyl chloride]]. |
NOHSO<sub>4</sub> is used in [[organic chemistry]] to prepare [[diazonium salt]]s from [[amine]]s, for example in the [[Sandmeyer reaction]]. Related NO-delivery reagents include [[nitrosonium tetrafluoroborate]] ([NO]BF<sub>4</sub>) and [[nitrosyl chloride]]. |
Revision as of 07:57, 21 April 2021
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Names | |
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IUPAC name
Nitrosylsulfuric acid
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Other names
nitrosonium bisulfate, chamber crystals
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Identifiers | |
3D model (JSmol)
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ChemSpider | |
ECHA InfoCard | 100.029.058 |
PubChem CID
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UNII | |
CompTox Dashboard (EPA)
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Properties | |
HNO5S | |
Molar mass | 127.08 g/mol |
Appearance | Pale yellow crystals[1] |
Density | 1.612 g/mL in 40% sulfuric acid soln |
Melting point | 70 °C (158 °F; 343 K)[1] |
Boiling point | Decomposes |
Decomposes | |
Solubility | Soluble in H2SO4[1] |
Hazards | |
Occupational safety and health (OHS/OSH): | |
Main hazards
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Oxidizer |
Related compounds | |
Other anions
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NOCl |
Other cations
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NaHSO4 |
Related compounds
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NOBF4 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Nitrosylsulfuric acid is the chemical compound with the formula NOHSO4. It is a colourless solid that is used industrially in the production of caprolactam,[2] and was formerly part of the lead chamber process for producing sulfuric acid. The compound is the mixed anhydride of sulfuric acid and nitrous acid.
In organic chemistry, it is used as a reagent for nitrosating, as a diazotizing agent, and as an oxidizing agent.[1]
Synthesis and reactions
A typical procedure entails dissolving sodium nitrite in cold sulfuric acid:[3][4]
- HNO2 + H2SO4 → NOHSO4 + H2O
It can also be prepared by the reaction of nitric acid and sulfur dioxide.[5]
NOHSO4 is used in organic chemistry to prepare diazonium salts from amines, for example in the Sandmeyer reaction. Related NO-delivery reagents include nitrosonium tetrafluoroborate ([NO]BF4) and nitrosyl chloride.
In industry, the nitrosodecarboxylation reaction between nitrosylsulfuric acid and cyclohexanecarboxylic acid is used to generate caprolactam:[2]
Safety
Nitrosylsulfuric acid is a hazardous material and precautions are indicated.[1]
References
- ^ a b c d e George A. Olah, G. K. Surya Prakash, Qi Wang, Xing-Ya Li (2001). Nitrosylsulfuric Acid. doi:10.1002/047084289X.rn060. ISBN 978-0471936237.
{{cite book}}
:|journal=
ignored (help)CS1 maint: multiple names: authors list (link) - ^ a b Ritz, J.; Fuchs, H.; Kieczka, H.; Moran, W. C. (2002). "Caprolactam". Ullmann's Encyclopedia of Industrial Chemistry. Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a05_031. ISBN 978-3527306732.
- ^ Hodgson, H. H.; Mahadevan, A. P.; Ward, E. R. (1955). "1,4-Dinitronaphthalene". Organic Syntheses; Collected Volumes, vol. 3, p. 341. (diazodization followed by treatment with nitrite)
- ^ Sandin, R. B.; Cairns, T. L. (1943). "1,2,3-Triiodo-5-nitrobenzene". Organic Syntheses; Collected Volumes, vol. 2, p. 604. (diazodization followed by treatment with iodide)
- ^ Coleman, G. H.; Lillis, G. A.; Goheen, G. E. (1939). Nitrosyl Chloride. Inorganic Syntheses. Vol. 1. pp. 55–59. doi:10.1002/9780470132326.ch20. ISBN 9780470132326. This procedure generates the nitrosylsulfuric acid as an intermediate en route to NOCl.