FOX-7
Names | |
---|---|
IUPAC name
2,2-Dinitroethene-1,1-diamine
| |
Other names
FOX-7
FOX7 | |
Identifiers | |
3D model (JSmol)
|
|
ChemSpider | |
ECHA InfoCard | 100.130.630 |
EC Number |
|
PubChem CID
|
|
UNII | |
CompTox Dashboard (EPA)
|
|
| |
| |
Properties | |
C2H4N4O4 | |
Molar mass | 148.08 |
Density | 1.885 g cm−3 |
Melting point | 238 °C (460 °F; 511 K) (decomposes) |
Hazards | |
GHS labelling: | |
Danger | |
H201, H228, H302 | |
P210, P230, P240, P241, P250, P264, P270, P280, P301+P312, P330, P370+P378, P370+P380, P372, P373, P401, P501 | |
Explosive data | |
Friction sensitivity | >350N[1] |
Detonation velocity | 8870 m/s at density 1.885 g cm−3 (estimated) 8335 m/s at density 1.756 g cm−3 (measured, small-scale testing) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
|
FOX-7 or 1,1-diamino-2,2-dinitroethene (DADNE)[2] is an insensitive high explosive compound. It was first synthesized in 1998 by the Swedish National Defence Research Institute (FOA).[3]
FOX-7 is similar to the insensitive chemical compound TATB, which is a benzene ring compound with three amino and three nitro groups.[4] FOX-7 has a two-carbon backbone rather than a benzene ring, but the amino and nitro groups have similar effects in both cases according to published reports on sensitivity and chemical decay processes of FOX-7.[5] FOX-7 is stoichiometrically identical but structurally unrelated to RDX, a benchmark explosive for sensitivity and explosive power. By various measures of sensitivity, such as dropped-weight impact, friction force, temperature of ignition, and response to heating under confinement, it is less sensitive than RDX, while having performance slightly greater than the same.[1] FOX-7 is produced as of 2018 by EURENCO Bofors AB of Sweden,[6] having been made in batches up to 7kg in 2001.[7]
Its explosive properties appear extremely favorable; in addition to its insensitive properties, the detonation velocity of mixtures of 80% FOX-7 plus binders is as high as Composition B, and nearly pure FOX-7 based plastic bonded explosives are slightly superior to RDX.[8] FOX-7 has been calculated to have a detonation velocity of 8,870 m/s.[9]
Due to its small-scale production, the cost of FOX-7 is relatively high. However, the production is based on commercial starting material and the synthesis is uncomplicated.[10] The price is therefore predicted to fall as production scale increases. There is no current full scale use of FOX-7, but it is being tested at several military research centers. The need for less sensitive munitions is favorable, and therefore the most important incentive for testing FOX-7.
References
- ^ a b Ian J., Lochert (November 2001). FOX-7 - A New Insensitive Explosive (PDF) (Technical report). Fisherman's Bend, Victoria, Australia: Defense Science & Technology Organization. DSTO-TR-1238.
{{cite tech report}}
: CS1 maint: date and year (link) - ^ US Patent 6340780 - Method of preparing salts of dinitromethane
- ^ Bemm, U.; Östmark, H. (1998) "1,1-Diamino-2,2-dinitroethylene: a Novel Energetic Material with Infinite Layers in Two Dimensions". Acta Cryst C54: 1997-1999. doi:10.1107/S0108270198007987.
- ^ Hervé, Grégoire; Jacob, Guy; Latypov, Nikolaj (2005). "The reactivity of 1,1-diamino-2,2-dinitroethene (FOX-7)". Tetrahedron. 61 (28): 6743. doi:10.1016/j.tet.2005.05.010.
- ^ Anniyappan, M.; Talawar, M.B.; Gore, G.M.; Venugopalan, S.; Gandhe, B.R. (2006). "Synthesis, characterization and thermolysis of 1,1-diamino-2,2-dinitroethylene (FOX-7) and its salts". Journal of Hazardous Materials. 137 (2): 812–9. doi:10.1016/j.jhazmat.2006.03.034. PMID 16701943.
- ^ Sleadd, Bradley A.; Boruta, David T.; Clubb, Joseph W. (24 April 2018). Development of a CONUS manufacturing capability for FOX-7 (Technical report). National Defense Industrial Association.
{{cite tech report}}
: CS1 maint: date and year (link) - ^ Ostmark, Henric; Bergman, Helena; Bemm, Ulf; Goede, Patrick (6 July 2001). "Energetic Materials: Ignition, Combustion and Detonation". 2, 2-dinitro-ethene-1, 1-diamine(FOX-7)- Properties, analysis and scale-up. 32nd International Conference of ICT. Karlsruhe, Germany: Fraunhofer-Institut für Chemische Technologie. pp. 26-1–26-21. Archived from the original on 2018-05-04.
{{cite conference}}
: Unknown parameter|booktitle=
ignored (|book-title=
suggested) (help) - ^ Latypov, Nikolai V.; Bergman, Jan; Langlet, Abraham; Wellmar, Ulf; Bemm, Ulf (1998). "Synthesis and reactions of 1,1-diamino-2,2-dinitroethylene". Tetrahedron. 54 (38): 11525–11536. doi:10.1016/s0040-4020(98)00673-5.
- ^ Detonation and Sensitivity Properties of FOX-7 and Formulations Containing FOX-7, Karlsson et al., 2002, accessed Aug 25, 2005
- ^ US Patent 6312538 - Chemical compound suitable for use as an explosive, intermediate and method for preparing the compound
Further reading
- Sorescu, Dan C.; Boatz, Jerry A.; Thompson, Donald L. (2001). "Classical and Quantum-Mechanical Studies of Crystalline FOX-7 (1,1-Diamino-2,2-dinitroethylene)". The Journal of Physical Chemistry A. 105 (20): 5010. doi:10.1021/jp010289m.
- Evers, Jürgen; Klapötke, Thomas M.; Mayer, Peter; Oehlinger, Gilbert; Welch, Jan (2006). "Α- and β-FOX-7, Polymorphs of a High Energy Density Material, Studied by X-ray Single Crystal and Powder Investigations in the Temperature Range from 200 to 423 K". Inorganic Chemistry. 45 (13): 4996–5007. doi:10.1021/ic052150m. PMID 16780321.