Potassium formate: Difference between revisions

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 {{chembox
+| Verifiedfields = changed
-| verifiedrevid = 414182160
+| Watchedfields = changed
-| Reference=<ref>Olsen, J C (editor), ''Van Nostrand's Chemical Annual'', Chapman and Hall, London, 1934</ref>
+| verifiedrevid = 419113064
+| Name =
+| Reference = <ref>Olsen, J C (editor), ''Van Nostrand's Chemical Annual'', Chapman and Hall, London, 1934</ref>
 | ImageFile = Potassium formate.png
+| ImageFileL1 = Formate-3D-balls.png
+| ImageFileR1 = Potassium-3D.png
 | ImageSize = 120px
-| IUPACName = Potassium formate
+| PIN = Potassium formate
 | OtherNames =
 | Section1 = {{Chembox Identifiers
-| CASNo_Ref = {{cascite}}
+| CASNo_Ref = {{cascite|correct|CAS}}
 | CASNo = 590-29-4
+| UNII_Ref = {{fdacite|correct|FDA}}
-| PubChem = 2735122
-| RTECS = LQ9625000
+| UNII = 25I90B156L
+|  PubChem = 11539
-| SMILES = C([O-])=O.[K+]}}
+|  ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}
+| ChemSpiderID = 11054
+|  SMILES = C(=O)[O-].[K+]
+|  InChI = 1/CH2O2.K/c2-1-3;/h1H,(H,2,3);/q;+1/p-1
+|  InChIKey = WFIZEGIEIOHZCP-REWHXWOFAK
+|  StdInChI_Ref = {{stdinchicite|changed|chemspider}}
+| StdInChI = 1S/CH2O2.K/c2-1-3;/h1H,(H,2,3);/q;+1/p-1
+|  StdInChIKey_Ref = {{stdinchicite|changed|chemspider}}
+| StdInChIKey = WFIZEGIEIOHZCP-UHFFFAOYSA-M
+}}
 | Section2 = {{Chembox Properties
-| C=1|H=1|K=1|O=2
+| K=1|H=1|C=1|O=2
-| Appearance = colorless crystals <br> [[deliquescent]]
+| Appearance = Colorless [[deliquescent]] crystals
 | Density = 1.908 g/cm<sup>3</sup>
 | MeltingPtC = 167.5
 | BoilingPt = Decomposes
 | Solubility = 32.8 g/100 mL (0 °C) <br> 331 g/100 mL (25°C) <br> 657 g/100 mL (80 °C)
-| SolubleOther = soluble in [[alcohol]] <br> insoluble in [[ether]]
+| SolubleOther = soluble in [[ethanol|alcohol]] <br> insoluble in [[diethyl ether|ether]]
 | pKb = 10.25
 }}
 | Section3 = {{Chembox Hazards
+| GHSPictograms = {{GHS exclamation mark}}
-| MainHazards =
+| GHSSignalWord = '''Warning'''
-| FlashPt =
+| HPhrases = {{H-phrases|335|319|315}}
-| Autoignition = }}
+| PPhrases = {{P-phrases|261|302+352|280|305+351+338}}
+| LD50 = 5500 mg/kg (oral, mouse)
+}}
+| Section4 =
+| Section5 =
+| Section6 =
 }}
-'''Potassium formate''' is the [[potassium]] [[salt (chemistry)|salt]] of [[formic acid]].  It is an intermediate in the formate potash process for the production of potassium.<ref>''Concise Encyclopedia Chemistry'', Mary Eagleson (1994), page 888.  ISBN 978-3-11-011451-5</ref>  Potassium formate has also been studied as a potential environmentally-friendly deicing salt for use on roads.<ref>{{cite journal | author = Pasi P. Hellstén, Jani M. Salminen, Kirsten S. Jørgensen, and Taina H. Nystén | journal = Environ. Sci. Technol. | year = 2005 | volume = 39 | issue = 13 | pages = 5095–5100 | doi = 10.1021/es0482738 | pmid = 16053115 | title = Use of potassium formate in road winter deicing can reduce groundwater deterioration.}}</ref>
+'''Potassium formate''', HCO<sub>2</sub>K, HCOOK, or KHCO<sub>2</sub>, is the [[potassium]] [[salt (chemistry)|salt]] of [[formic acid]].  This strongly hygroscopic white solid<ref>{{Cite web|url=https://www.sigmaaldrich.com/MSDS/MSDS/DisplayMSDSPage.do?country=US&language=en&productNumber=294454&brand=ALDRICH&PageToGoToURL=https://www.sigmaaldrich.com/catalog/product/aldrich/294454?lang=en|title=MSDS - 294454|website=www.sigmaaldrich.com|access-date=2019-03-18}}</ref> is an intermediate in the formate potash process for the production of potassium.<ref>''Concise Encyclopedia Chemistry'', Mary Eagleson (1994), page 888.  {{ISBN|978-3-11-011451-5}}</ref>  Potassium formate has also been studied as a potential [[environmentally friendly]] deicing salt for use on roads.<ref>{{Cite web|title = Finnish Environment Institute > Main publications on the effect of de-icing chemicals on ground water|url = http://www.syke.fi/en-US/Research__Development/Research_and_development_projects/Projects/Migration_of_alternative_deicing_chemicals_in_aquifers_MIDAS/Main_publications_on_the_effect_of_deicing_chemicals_on_ground_water|website = www.syke.fi|access-date = 2015-11-18}}</ref><ref>{{cite journal |author1=Pasi P. Hellstén |author2=Jani M. Salminen |author3=Kirsten S. Jørgensen |author4=Taina H. Nystén  |name-list-style=amp | journal = Environ. Sci. Technol. | year = 2005 | volume = 39 | issue = 13 | pages = 5095–5100 | doi = 10.1021/es0482738 | pmid = 16053115 | title = Use of potassium formate in road winter deicing can reduce groundwater deterioration|bibcode=2005EnST...39.5095H }}</ref> It has also been suggested for use in a less corrosive [[liquid desiccant]].<ref>{{Cite web|url=https://www.cibsejournal.com/cpd/modules/2014-12/|title = Module 71: Liquid desiccants for dehumidification in building air conditioning systems}}</ref> A 52% solution of potassium formate has a freezing point of {{convert|-60|C}}.<ref>{{Cite web|url=https://aerospace.basf.com/potassium-formate-for-runway-deicing.html|title = Potassium Formate for Runway Deicing}}</ref>  Potassium formate brines are sometimes used for heat transfer, despite being much more corrosive than many other liquid coolants, especially to zinc and aluminum but even to many steels,<ref>{{Cite web
+|title=Brines and antifreeze
+|url=https://www.hydratech.co.uk/Technical/Brine-as-a-heat-transfer-fluid-and-antifreeze/0/33
+|accessdate=2022-01-16
+}}</ref>
+though some formulations are compatible with aluminum and steels.<ref>{{Cite web
+|title=Technical information on "TYFOXIT F15-F50: Ready-to-Use, High-Performance Ultra Low Viscous Secondary Refrigerants for Applications Down to –50 °C"
+|url=https://tyfo.de/downloads/TYFOXIT-F15-F50_en_TI.pdf
+|accessdate=2022-01-16
+}}</ref>
 ==References==
@@ Line 38: / Line 68: @@
 [[Category:Potassium compounds]]
-{{organic-compound-stub}}
+{{organic-compound-stub}}
-[[cs:Mravenčan draselný]]
-[[de:Kaliumformiat]]
-[[nl:Kaliumformiaat]]
-[[pl:Mrówczan potasu]]
-[[ru:Формиат калия]]
-[[fi:Kaliumformiaatti]]
-[[sv:Kaliumformiat]]
-[[zh:甲酸钾]]