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Zirconium disulfide: Difference between revisions

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{{chembox
{{chembox
| verifiedrevid = 333719065
| Name = Zirconium(IV) sulfide
| Name = Zirconium(IV) sulfide
| Reference = <ref name="hand">
| Reference = <ref name="hand">
{{Citation
{{Citation
| last = Lide
| last = Lide
| first = David R.
| first = David R.
| author-link =
| year = 1998
| title = Handbook of Chemistry and Physics
| last2 =
| first2 =
| edition = 87
| location = Boca Raton, Florida
| author2-link =
| publisher = CRC Press
| publication-date =
| isbn = 0-8493-0594-2
| date =
| year = 1998
| pages = 4–96
| title = Handbook of Chemistry and Physics
| edition = 87
| volume =
| series =
| publication-place = Boca Raton, FL
| place =
| publisher = CRC Press
| id =
| isbn = 0849305942
| doi =
| oclc =
| pages = 4–96
| url =
| accessdate =
}}</ref>
}}</ref>
| ImageFile=Cadmium-iodide-3D-layers.png
| ImageFile =Cadmium-iodide-3D-layers.png
| IUPACName = Zirconium(IV) sulfide
| IUPACName = Zirconium(IV) sulfide
| OtherNames =
| OtherNames =
| Section1 = {{Chembox Identifiers
|Section1={{Chembox Identifiers
| CASNo = 12039-15-5
| CASNo = 12039-15-5
| EINECS = 234-885-1
| PubChem = 10219558
| ChemSpiderID = 8395050
| StdInChI=1S/2S.Zr/q2*-2;+4
| StdInChIKey = XWPGCGMKBKONAU-UHFFFAOYSA-N
| SMILES = [S-2].[S-2].[Zr+4]
}}
}}
| Section2 = {{Chembox Properties
|Section2={{Chembox Properties
| Formula = ZrS<sub>2</sub>
| Formula = ZrS<sub>2</sub>
| MolarMass = 155.356 g/mol
| MolarMass = 155.356 g/mol
| Appearance = red-brown crystals
| Appearance = red-brown crystals
| Density = 3.82 g/cm<sup>3</sup>
| Density = 3.82 g/cm<sup>3</sup>
| MeltingPt = 1480°C
| MeltingPtC = 1480
| BoilingPt =
| BoilingPt =
| Soluble = insoluble
| Solubility = insoluble
}}
}}
| Section3 = {{Chembox Structure
|Section3={{Chembox Structure
| Coordination = octahedral
| Coordination = octahedral
| CrystalStruct = [[Rhombohedral]], [[Pearson symbol|hP3]], SpaceGroup = P-3m1, No. 164
| CrystalStruct = [[Rhombohedral]], [[Pearson symbol|hP3]]|SpaceGroup = P-3m1, No. 164
| Dipole =
| Dipole =
}}
}}
| Section7 = {{Chembox Hazards
|Section7={{Chembox Hazards
| ExternalSDS = [http://www.strem.com/catalog/printer.php?type=msds&catalog_number=93-4033 MSDS]
| EUClass = not listed
| ExternalMSDS = [http://www.strem.com/catalog/printer.php?type=msds&catalog_number=93-4033 MSDS]
}}
}}
}}
}}
'''Zirconium(IV) sulfide''' is the [[inorganic compound]] with the formula [[Zirconium|Zr]][[Sulfide|S<sub>2</sub>]]. It is a violet-brown solid. It adopts a layered structure similar to that of [[cadmium iodide]].


Like the closely related [[titanium disulfide]], ZrS<sub>2</sub> is prepared by heating sulfur and zirconium metal. It can be purified by [[vapor transport]] using iodine.<ref>Lawrence E. Conroy "Group IV Sulfides" Inorganic Synthesis 1970, XII, 158. {{doi|10.1002/9780470132432.ch28}}</ref>
'''Zirconium(IV) sulfide''' ([[Zirconium|Zr]][[Sulfur|S<sub>2</sub>]]) is a [[chemical compound]].


==References==
==References==
{{reflist}}
{{reflist}}

{{Zirconium compounds}}
{{Zirconium compounds}}
{{Sulfides}}
{{sulfur compounds}}


[[Category:Sulfides]]
[[Category:Disulfides]]
[[Category:Zirconium compounds]]
[[Category:Zirconium(IV) compounds]]
[[Category:Transition metal dichalcogenides]]




{{inorganic-compound-stub}}
{{inorganic-compound-stub}}

[[ar:كبريتيد زركونيوم رباعي]]