Abstract
Substitution of carbon for sulfur in a potent 13-membered cyclic disulfide containing peptide was accomplished via an intramolecular Wittig reaction and resulted in a series of 'carba' analogues. Potency in the VCAM-VLA-4 assay was sensitive to ring size and lower than that of the parent disulfide.
MeSH terms
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Integrin alpha4beta1
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Integrins / antagonists & inhibitors*
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Molecular Mimicry
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Peptides, Cyclic / chemistry
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Peptides, Cyclic / pharmacology*
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Receptors, Lymphocyte Homing / antagonists & inhibitors*
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Vascular Cell Adhesion Molecule-1 / drug effects*
Substances
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Integrin alpha4beta1
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Integrins
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Peptides, Cyclic
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Receptors, Lymphocyte Homing
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Vascular Cell Adhesion Molecule-1