Fast homogeneous assay for plasma procarboxypeptidase U

Clin Chem Lab Med. 2001 Sep;39(9):806-10. doi: 10.1515/CCLM.2001.133.

Abstract

Carboxypeptidase U (EC 3.4.17.20, CPU, TAFIa) is a novel determinant of the fibrinolytic rate. It circulates as an inactive zymogen, procarboxypeptidase U, which becomes active during the process of coagulation. We developed a high throughput method on microtiter plates for the determination of the procarboxypeptidase U concentration in human plasma samples. Following activation of procarboxypeptidase U by thrombin-thrombomodulin, the resulting enzyme activity cleaves p-OH-Hip-Arg and the generated p-OH-hippuric acid is converted by hippuricase to p-hydroxybenzoic acid and glycine. Finally, oxidative coupling of p-hydroxybenzoic acid with 4-aminoantipyrine by NaIO4 forms the quinoneimine dye. The absorbance of the latter dye is determined at 506 nm in a microtiter plate reader. A mean value of 620 U/l was found, with a CV of 3.0% within-run and 4.3% between-run. The assay showed a good correlation with the activities observed using a HPLC assay as reference method (n = 25, r = 0.979). The presented method enables the routine analysis of large sample pools in clinical setting.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adult
  • Aged
  • Amidohydrolases / metabolism
  • Carboxypeptidase B2 / blood*
  • Enzyme Activation
  • Female
  • Fibrinolysis
  • Hippurates / metabolism
  • Humans
  • Male
  • Middle Aged
  • Reference Values
  • Reproducibility of Results
  • Sensitivity and Specificity
  • Thrombin
  • Thrombomodulin

Substances

  • Hippurates
  • Thrombomodulin
  • Carboxypeptidase B2
  • Thrombin
  • Amidohydrolases
  • aminoacylase I
  • hippuric acid