Liquid crystalline nanowires in porous alumina: geometric confinement versus influence of pore walls

Nano Lett. 2005 Mar;5(3):429-34. doi: 10.1021/nl0481728.

Abstract

Aligned liquid crystalline nanowires within ordered porous alumina templates show a pronounced texture on a macroscopic scale. We have investigated the influence of the geometric confinement and the nature of the pore walls on the mesophase formation by means of X-ray diffraction. The apparent texture is the result of a complex interplay of the pore geometry, interfacial phenomena, and the thermal history. Pores with a diameter of a few hundred nm guide the mesophase formation more efficiently than those with a diameter below 100 nm.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aluminum Oxide / chemistry*
  • Crystallization / methods*
  • Materials Testing
  • Molecular Conformation
  • Nanotechnology / methods*
  • Nanotubes / analysis
  • Nanotubes / chemistry*
  • Nanotubes / ultrastructure*
  • Particle Size
  • Phase Transition
  • Porosity
  • Lösungen
  • X-Ray Diffraction

Substances

  • Lösungen
  • Aluminum Oxide