Virus-enabled synthesis and assembly of nanowires for lithium ion battery electrodes

Science. 2006 May 12;312(5775):885-8. doi: 10.1126/science.1122716. Epub 2006 Apr 6.

Abstract

The selection and assembly of materials are central issues in the development of smaller, more flexible batteries. Cobalt oxide has shown excellent electrochemical cycling properties and is thus under consideration as an electrode for advanced lithium batteries. We used viruses to synthesize and assemble nanowires of cobalt oxide at room temperature. By incorporating gold-binding peptides into the filament coat, we formed hybrid gold-cobalt oxide wires that improved battery capacity. Combining virus-templated synthesis at the peptide level and methods for controlling two-dimensional assembly of viruses on polyelectrolyte multilayers provides a systematic platform for integrating these nanomaterials to form thin, flexible lithium ion batteries.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Bacteriophage M13* / chemistry
  • Bacteriophage M13* / genetics
  • Capsid Proteins / chemistry
  • Cobalt* / chemistry
  • Crystallization
  • Electric Conductivity
  • Electric Power Supplies*
  • Electrochemistry
  • Electrodes*
  • Gold
  • Lithium
  • Microscopy, Electron, Transmission
  • Nanostructures*
  • Nanotechnology*
  • Oxides* / chemistry
  • Peptide Library
  • Protein Engineering
  • Temperature
  • Thermodynamics

Substances

  • Capsid Proteins
  • Oxides
  • Peptide Library
  • Cobalt
  • Gold
  • Lithium
  • cobalt oxide