Recent developments in the mechanistic enzymology of the ATP-dependent Lon protease from Escherichia coli: highlights from kinetic studies

Mol Biosyst. 2006 Oct;2(10):477-83. doi: 10.1039/b609936j. Epub 2006 Aug 24.

Abstract

Lon protease, also known as protease La, is one of the simplest ATP-dependent proteases that plays vital roles in maintaining cellular functions by selectively eliminating misfolded, damaged and certain short-lived regulatory proteins. Although Lon is a homo-oligomer, each subunit of Lon contains both an ATPase and a protease active site. This relatively simple architecture compared to other hetero-oligomeric ATP-dependent proteases such as the proteasome makes Lon a useful paradigm for studying the mechanism of ATP-dependent proteolysis. In this article, we survey some recent developments in the mechanistic characterization of Lon with an emphasis on the utilization of pre-steady-state enzyme kinetic techniques to determine the timing of the ATPase and peptidase activities of the enzyme.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't
  • Review

MeSH terms

  • Adenosine Triphosphate / metabolism*
  • Amino Acid Sequence
  • Escherichia coli / enzymology*
  • Escherichia coli Proteins / chemistry*
  • Escherichia coli Proteins / metabolism
  • Fluorescence Resonance Energy Transfer / methods*
  • Hydrolysis
  • Kinetics
  • Models, Molecular
  • Molecular Sequence Data
  • Peptides / metabolism
  • Protease La / chemistry*
  • Protease La / metabolism

Substances

  • Escherichia coli Proteins
  • Peptides
  • Adenosine Triphosphate
  • Protease La