Hydrothermal syntheses and structural characterizations of organic-inorganic hybrid materials of the M(II)-ligand/vanadium oxide system (M(II) = Mn(II), Cu(II) and Zn(II); ligand = 2,2'-bipyridine and 1,10-phenanthroline)

Zhi-Hui Yi; Xiao-Bing Cui; Xiao Zhang; Jie-Hui Yu; Jing Lu; Ji-Qing Xu; Guang-Di Yang; Tie-Gang Wang; Hai-Hui Yu; Wei-Jie Duan

doi:10.1039/b618461h

Hydrothermal syntheses and structural characterizations of organic-inorganic hybrid materials of the M(II)-ligand/vanadium oxide system (M(II) = Mn(II), Cu(II) and Zn(II); ligand = 2,2'-bipyridine and 1,10-phenanthroline)

Dalton Trans. 2007 Jun 7:(21):2115-20. doi: 10.1039/b618461h. Epub 2007 Apr 3.

Authors

Zhi-Hui Yi¹, Xiao-Bing Cui, Xiao Zhang, Jie-Hui Yu, Jing Lu, Ji-Qing Xu, Guang-Di Yang, Tie-Gang Wang, Hai-Hui Yu, Wei-Jie Duan

Affiliation

¹ College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130023, China.

PMID: 17514331
DOI: 10.1039/b618461h

Abstract

Three organic-inorganic hybrid compounds [Mn(bpy)V(bpy)V(3)O(11)] (bpy = 2,2'-bipyridine) (1), [Cu(bpy)V(2)O(6)] (2) and [Zn(phen)3][V(2)O(6)].10H(2)O (phen = 1,10-phenanthroline) (3) have been synthesized hydrothermally. Single crystal X-ray diffraction analyses revealed that compound 1 is the first example of bpy units coordinating to different transition metals in one molecule. Compound 2 is a new isomer of [Cu(bpy)V(2)O(6)] which was named the gamma-isomer by us. In compound 3, a 2-D water sheet with big holes filled by the "naked" [V(4)O(12)](4-) clusters is found.